改性HZSM-5分子筛的苯与液化气中的C4混合烯烃的烷基化反应论文.doc

毕 业 设 计（论 文） 基于改性HZSM-5分子筛的 苯与液化气中的C4 摘要 实验室通常使用氢氟酸或者氯化铝作为催化剂进行烷基化反应得到C4~C14烷基苯的混合物。但是由于HF和 本文通过对ZSM-5催化剂进行改性，并基于改性ZSM-5，进行苯与液化气C4 结果表明，改性ZSM-5催化剂催化苯与液化气 QUOTE 混合烯烃的烷基化反应，具有较好的烷基化选择性和烯烃转化率。基于改性ZSM-5催化剂的苯与 QUOTE 混合烯烃的气相烷基化反应的较佳工艺条件为：反应温度330~340℃，反应压力1.5~1.8MPa，苯烯摩尔比2.4~2.7，烯烃空速0.8~1h-1。 关键词：烷基化反应 直链烷基苯 ZSM-5 液化气 Abstract Linear alkylbenzene (LAB) is a basic and important petrochemical interme-diate for manufacturing of synthetic detergent.LAB is usually mixture of C9~C14 alkylbenzene obtained by the alkylation of benzene with mixed olefins us ing hydrofluoric acid or aluminum chloride as the catalysts. However, due to strong corrosive HF and AlCl_3 for demanding production facilities, process complex and serious environmental pollution in recent years, the development of environment-friendly catalyst for widespread concern. Especially in todays environment is deteriorating, a growing awareness of the human environment, motor gasoline aromatics content, olefin content, vapor pressure under restricted conditions, alkylation of oil as the ideal components of reformulated gasoline, the production of it More and more attention. Production process from the point of view, than the olefin alkylation process composite technology, can more fully use the advantages of refinery gas resources. Based on the modified ZSM-5 catalyst and is based on modified ZSM-5, benzene and liquefied petroleum gas C4 mixed olefin alkylation reaction. Orthogonal method of the reaction temperature, reaction pressure, the molar ratio of phenylene, feed space velocity and other factors on the impact of alkylation reaction. The results showed that the modified ZSM-5 catalyst gas mixture of benzene and olefin alkylation, alkylation with good selectivity and olefin conversion. Based on modified ZSM-5 catalyst of benzene and mixed olefin gas phase alkylation of better conditions were: reaction temperature 330~340℃, reaction pressure 1.5~1.8 MPa, phenylene ethylene molar ratio of 2.4~2.7 , airspeed