毕业论文-基于两种双吡啶双酰胺配体的钴配合物的水热合成、结构性质研究.docVIP

本科毕业论文 题 目： 基于两种双吡啶双酰胺配体 的钴配合物的水热合成、结 构和性质研究 学生姓名： 指导教师： 院 系： 化学与化工与食品安全学院 专 业： 化学教育 班 级： 论文答辩日期：2012.05.30 基于两种双吡啶双酰胺配体的钴配 合物的水热合成、结构和性质研究 化学化工学院 摘要: 在本论文中，选择半刚性配体N,N′-双(3-吡啶)环己烷-1,4-双甲酰胺(3-bpcd)和刚性配体N,N′-双(3-吡啶)苯-1,4-双甲酰胺(3-bpbd)做为主要配体，间苯二甲酸(1,3-H2BDC)做为辅助桥连配体与过渡金属钴离子在水热条件下进行反应，合成了2个新的配合物[Co(3-bpcd)(1,3-BDC)(H2O)3]·H2O (1) 和[Co(3-bpbd)(1,3-BDC)]·H2O (2)，并且通过元素分析、红外光谱和X-射线单晶衍射进行表征。X-射线单晶衍射分析结果表明1首先通过3-bpcd和1,3-BDC连成一种正弦曲线状的一维配位聚合物链状结构，再通过氢键作用形成了一个三维的超分子网络骨架。配合物2 是基于两种桥连配体3-bpcd 和 1,3-BDC的二维配位聚合物层，在二维层中包含两种一维链结构(Co-3-bpbd 链和Co-1,3-BDC链)，配合物2的相邻层在氢键作用下连接形成三维超分子网络结构。我们以配合物1为例，对其进行了热重、荧光性质和其修饰电极(1-CPE)电化学行为的研究。 关键词：水热合成，钴配合物，晶体结构，性质 Hydrothermal Syntheses, Structures and Properties of Cobalt Complexes Based on Two Bis-pyridyl-bis-amide Ligands Zhang Xia College of Chemistry, Chemical Engineering and Food Safety Abstract: In my paper, the semi-rigid ligand N,N′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide (3-bpcd) and rigid ligand N,N′-bis(pyridin-3-yl)benzene-1,4-dicarboxamide (3-bpbd) have been selected as the main ligands, and 1,3-benzenedicarboxylate (1,3-H2BDC) has been used as the auxiliary bridging ligand to react with transition metal cobalt ions under hydrothermal conditions. Two new complexes, [Co(3-bpcd)(1,3-BDC)(H2O)3]·H2O (1) and [Co(3-bpbd)(1,3-BDC)]·H2O (2), have been synthesized and characterized by elemental analyses, IR and single-crystal X-ray diffraction. Complex 1 exhibits a one-dimensional (1D) sinusoid-like chain based on 3-bpcd and 1,3-BDC, which is further assembled into a three-dimensional (3D) supramolecular framework through hydrogen bonding interactions. Complex 2 is a two-dimensional (2D) coordination polymer layer composed of bridging ligands 3-bpbd and 1,3-BDC, and there are exist two kinds of 1D chains (Co-3-bpbd chain and Co-1,3-BDC chain) in the 2D layer. The adjacent 2D polymer layers are connected by hydrogen bonding interactions to form a 3D supramolecular network of complex 2. Taking the co