反渗透膜处理PTA 精制单元废水研究.pdfVIP

福州大学学报(自然科学版) Vol. 38 No.2 第38 卷第2 期 2010 主主且 Journal of F皿hou Ulliver百ity( Natural Science) Apr. 2010 文章编号:1∞0-2243(2010)02 -0303-06 反渗透膜处理 PTA 精制单元废水研究 邱挺，洪素芬，郭凌宇，吴燕翔 (福州大学化学化工学院，福建福州 350108) 摘要:采用反渗透膜法处理PfA 精制单元废水，探讨了反渗透工艺条件如回收率、操作压力、料液温度等对膜 性能的影响，从中得出较佳的工艺条件.同时，将反渗透的浓缩水回流到集水池中，结果表明反渗透透过水仍 然可以符合工艺指标.此外，还考察了物理清洗及不同的化学清洗剂对膜通量的恢复情况.结果表明，化学清 洗的效果明显优于物理清洗;而在化学清洗剂中， NaOH 榕液对于反渗透膜的膜通量有较好恢复作用. 关键词:精对苯二甲酸;废水;反渗透膜 文献标识码:A 中国分类号:1币28.8 TreatInent of PTA wastewater by reverse osmosis membrane QIU Ting , HONG 5u - fen , GUO Ling- 归， WU Yan - xiang (College of Chemistry and Chermcal Engineering , Fuzhou Ulliversity , Fuzhou , Fujian 350108 , China) Abstract: PTA wastewater was disposed by reverse osmosis membrane. And the influence of operation conditions such as recovery rate , pressure , and temperature on the perfOlmance of reverse osmosis was discussed. The best operation conditions were obtained. Meanwhile , concentration outflow of reverse osmosis were recycled ωthe feed tank , and the penneate flow could still meet the PI1∞ess require- ment. Furthenllore , the recovery of membrane flux was investigated wi由 physical washing and chemi- cal washing. The results showed that the effect of the latter was better. Among different chemical cleaning agents , NaOH solution has best effect on the recovery of reverse osmosis flux. Keywords: pure terephtha1ic acid; wastewater; reverse osmosis membrane 精对苯二甲酸(凹A) 是一种非常重要的有机化工原料，广泛应用于聚醋工业和其他化工工业生产中. 在町A 精制工段，粗对苯二甲酸(CTA) 在高温高压下溶解于水中，流经知