苯基丙酸化学还原法制备手性纳米银粒子的研究化学毕业论文.doc

2-苯基丙酸化学还原法制备手性纳米银粒子的研究 摘 要 本实验采用化学还原法，利用硼氢化钠为还原剂，2-苯基丙酸为稳定剂和手性诱导剂制备了手性纳米银粒子。探讨了硝酸银与硼氢化钠的比例，加入手性液体2-苯基丙酸的用量，硝酸银浓度和温度对纳米银粒子制备的影响；并改变滴加顺序，之后用温度来判断手性纳米银粒子的稳定性。用紫外-可见吸收光谱对纳米银粒子和手性纳米银粒子的情况进行表征。结果表明，在硼氢化钠与硝酸银的摩尔比为3:1，手性液体2-苯基丙酸加入得出结论为1:3:6,硝酸银浓度为0.001摩尔每升和硼氢化钠浓度为0.002摩尔每升为最佳浓度，温度为50摄氏度制备了小颗粒且分布均匀、稳定性高的纳米银粒子，并且纳米银粒子在水中具有良好的分散性；手性分子可能很好的修饰到纳米银粒子表面。 关键词：纳米银粒子；2-苯基丙酸；化学还原法；手性；稳定性 2-BENZENE RADICLE C THE SOUR CHEMISTRY REDUCTION METHOD MAKE THE RESEARCH OF THE HAND NA RICE SILVER GRAIN SON ABSTRACT This experiment adopts a chemistry Reduction Method and makes use of Peng hydrogen to turn the sodium as revivification, 2-benzene radicle C is sour are that stabilizing agent and hand inducement made the hand Na rice silver grain son.Inquired into silver nitrate and Peng hydrogen turning the proportion of sodium, join a hand liquid 2-benzene radicle C sour dosage, silver nitrate density and the influence of the temperature upon the Na rice silver grain son making;Combine change drop to add sequence, use the stability that the temperature judges the hand Na rice silver grain son after.Use a purple outside-it is thus clear that absorb a circumstance of spectrum to the Na rice silver grain son and the hand Na rice silver grain son to carry on token.Express that the Mo Er that turns sodium and silver nitrate in the Peng hydrogen compares to 3 as a result:1, hand liquid 2-benzene radicle C is sour to join conclusion is 1:3:6, the silver nitrate density rises each time for 0.001 Mo Ers and the Peng hydrogen turn the sodium density as 0.002 Mo Ers to advance to the best density each time, the temperature makes small grain for 50 Celsius degrees and distributes even, stability Gao of the Na rice silver grain son, and the Na rice silver grain the son has good dispersion in the water;Hand member may the good modifier arrive the Na rice silver grain sub- surface. Key words: The Na rice silver grain son; 2-benzene radicle C is sour; Chemistry Reduction Method; Hand; Stability  目 录 1前言-----