固体碱催化剂的合成与表征.pdfVIP

固体碱催化剂的合成与表征 摘 要 本课题采用负载和氮化两种方法制备固体碱催化剂。用浸渍或固相混合研磨的 3 2 3 3 2 2 方法，将 KNO 、KOH 、K CO 、Mg(NO ) 、Ba(OH) 等碱金属及碱土金属负载到拟 薄水铝石等载体上，再经真空焙烧或微波辐射制得固体碱催化剂，对催化剂的比表 面和碱量进行了表征，结果表明，将 K2 CO3 用研磨/ 辐射负载到拟薄水铝石上，当 K + 含量为 30 ％时所得催化剂的碱量达到最大。 /N 为 3/1 的混合气对 APO-5 分子筛进行程序升温氮化处理，用酸碱滴定 用 H2 2 法测定了氮化分子筛的碱量，并用原位 FTIR 测定了氮化分子筛的骨架特征。结果表 明，升温速率为 0.1℃/min，终温达到 800℃所得催化剂碱量最大。 用部分碱量较大的催化剂进行了酯交换法合成碳酸二甲酯（DMC）的探索实验， 结果表明，固体碱对酯交换法合成碳酸二甲酯具有一定的活性和选择性。 关键词 固体碱 负载 磷铝分子筛 氮化物 Synthesis and characterization of solid base catalysts Chen qiao (Facutly Of Materials Chemical Engineering, Beijing Institute Of Petro-chemical Techmology,102617) Abstract Two kinds of methods preparing solid alkali catalyst were studied in this paper,they are loading and nitrogenation.At potassium nitrate,grade alkaline-earth metal loads reach and plan potassium hydroxide thin diaspore,etc. At the carrier potassium carbonate , potassium hydroxide with the methods of flooding, grind, radiation. Roast by vacuum and microwave radiations make alkali catalyst more solid, at surface and alkali quantity signify one that is to catalyst,the result shows , potassium carbonate being loaded with grinding/radiation to reach thin diaspore, When K content is 30%, can receive the alkali and measure very big catalyst . Deal APO-5 molecilar sieve with mixing gas(H2/N2 is 3/1)by temperature programming nitrogenation, determine the alkali quanta with acid base titration and determine the character of framework with FTIR. The result shows , when speed is 0.1 ℃/min and the last empera