电镀污泥酸浸出液中铜和镍分离的研究.pdfVIP

11 1 无机盐工业 第42卷 第8期 IN0RGANIC CHEMICALS INDUSTRY 2010年8月 电镀污泥酸浸出液中铜和镍分离的研究 杨 春 ，刘定富 ，龙 霞 (1．贵阳中医学院，贵州贵阳550001；2．贵州大学) 摘 要：根据某电镀污泥酸浸出液中所含的铜(11)和镍(11)化学性质的差异，分别采用氨水分步沉淀法、硫 化钠选择沉淀法和铁粉置换法进行铜(II)和镍(II)分离的实验研究，考察溶液pH、硫化钠用量及铁粉用量对分离 效果的影响，根据溶度积理论及电化学理论简要阐述溶液中铜(11)和镍(Ⅱ)分离的原理。结果表明：在适当条件 下，硫化钠可以选择性地沉淀混合溶液中的铜(Ⅱ)，铁粉也可以优先置换混合溶液中的铜(II)，从而实现电镀污 泥酸浸出液中铜和镍的分离。 关键词：电镀污泥；酸浸出液；Cu“；Ni“ 中图分类号：TQ153 文献标识码：A 文章编号：1006—4990(2010)08—0044—03 Study on separation of Cu and Ni in acid leaching solution of electroplating sludge Yang Chun ，Liu Dingfu ，Long Xia (1．Guiyang College of Traditional Chinese Medwine，Gu@ang 550001，China；2．Gu~hou University) Abstract：According to different chemical properties of the Cu and Ni in a certain acid leaching solution of electro- plating sludge，the separation experiment of Cu and Ni was studied by ammonia fractional precipitation method，sodium sulfide selective precipitation method，and iron replacement method，respectively．Influences of solution pH，sodium sulfide dosage，and iron dosage on the separation effect were investigated．Then the separation principle of Cu and Ni was brieb ly introduced based Oil solubility product theory and electrochemical theory．Results showed that under appropriate condi— tions sodium sulfide can selectively precipitate Cu in the mixture solution and iron can also give priority to replace Cu in the mixture solution so as to achieve separation of Cu and Ni in acid leaching solution of electroplating sludge． Key words：electroplating sludge；acid leaching solution；Cu ；Ni 电镀生产过程中产生的含铬、铜、镍、锌、锡及铁 析。 等金属离子的废水一般采用化学沉淀法进行