N掺杂TiO2纳米管阵列的制备及催化性能研究 材料毕业论文.docVIP

目 录 摘 要 1 引 言 2 1 实验部 2 1.1 仪器与试剂 2 1.2 实验方法 3 2 结果与讨论 4 2.1 N掺杂TiO2纳米管阵列SEM和XRD的表征分析 4 2.2 红外及UV-Vis实验结果 7 2.3 光催化实验 11 3 结 论 12 参考文献 13 致谢 15 N掺杂TiO2纳米管阵列的制备及催化性能研究 摘 要：分别以氨水、乙二胺、尿素为氮源，利用阳极氧化法和湿化学法合成有机氮掺杂二氧化钛纳米管阵列。以不同含量的(NH4)2SO4为氮源，利用阳极氧化法合成无机氮掺杂二氧化钛纳米管阵列。通过扫描电镜(SEM)、X射线衍射(XRD)等表征方法对N掺杂TiO2纳米管形貌、晶形和氮元素掺杂方式进行分析。结果表明，TiO2纳米管有序排列并垂直生长在钛片基底表面。氮元素掺杂阻碍TiO2晶粒的增长，抑制锐钛矿向金红石的转变，且无机氮比有机氮更容易进入TiO2晶格中。并通过紫外线光催化降解乙酰甲胺磷，研究氮元素掺杂方式与紫外线光催化活性的关系。不同氮源条件下，以氨水为氮源降解率最高。相同氮源不同掺氮量，以0.5wt%的NH4F为氮源降解率最佳。 关键字：TiO2纳米管阵列；氮掺杂；光催化；乙酰甲胺磷 Research on Preparation of Nitrogen Doped TiO2 Nanotube Arrays and Photocatalytic Properties Abstract: Different nitrogen doped titanium dioxide nanotube arrays were preformed by electrochemical and wet chemical method by using ammonia，ethylenediamine，urea as nitrogen source respectivelyWith different contents (NH4)2SO4 as nitrogen source， nitrogen doped titanium dioxide nanotube arrays．The samples were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD)．The relationship between nitrogen doping behaviors was studied．The result indicated that highly ordered TiO2 nanotube arrays were grown on titanium substrates，inhibiting the transformation of anatase to rutile，and inorganic nitrogen than organic nitrogen into the TiO2 latticeThe result showed that highly ordered TiO2 nanotube arrays were grown on titanium substrates．And UV photocatalytic property was studied by the experiment of pesticides．The highest degradation rates under different nitrogen to ammonia as the nitrogen source．The same with different content nitrogen source of nitrogen to 0.5 wt % (NH4)2SO4 as nitrogen source degradation rate is the best． Key Words：TiO2 nanotube arrays；Nitrogen doped；Photocatalysis；Acephate 引 言 随着经济的发展，环境问题日益严重，在环境治理方面，半导体多相光催化技术有巨大的应用潜力，从而引起广泛的重视。二氧化钛以其化学性质稳定、难容、无毒、价格低廉且不引起二次污染等特点而成为研究最多的光催化剂。而且采用电化学阳极氧化技术制备的TiO2纳米管阵列形貌规整，纳米管分布均匀排列有序。纳米管直接在钛片表面生长，与金属钛导电基结合牢固结构稳定性高，所制备的纳米管阵列容易回收和重复使用[1-5]。另外，其高度有序的阵列结构和纳米管之间极低的团聚程度也决定了TiO2 纳米管阵列高的量子效应。由于二氧化钛