高级氧化工艺去除小分子羧酸的对比研究_毕业论文.doc

本科生毕业论文（设计） 摘要 Abstract Abstract The subject takes the Advanced Treatment method，or Advanced Oxidation Technology (Process) to removal of the small molecule carboxylic acids. The liquid chromatograpHy is used to determine the small molecule carboxylic acids. The selecting of the three advanced oxidation process are as follows: ozone oxidation，Fenton oxidation process and pHotocatalytic oxidation process. The targets for removal are formic acid，oxalic acid and salicylic acid. By comparing with the various experimental removal processes to determine the merits and select optimal reaction conditions. The result of the experiments proved that the ozone oxidation process is not suitable as a process of removing for the removal of the small molecular carboxylic acid for its removal rate is very low. However，for the reactor containing 500mL small molecule carboxylic acid，the conditions of the experiments are as follows:under the condition of pH=3，H2O2 is added in an amount of 0.36mol，Fe2+ is added in an amount of 1mmol and the reaction time is 20min.It makes that the Fenton oxidation process through experiments allowed the removal rate of the small molecules acid reached more than 96%，so the removal efficiency is very prominent；For the pHotocatalytic oxidation process，the choice is UV/H2O2 hypHenated techniques. In the condition of the reactor containing 500mL small molecule carboxylic acid，the initial reaction pH = 4，H2O2 addition is 0.48mol and the reaction time is 40min，the removal rate can up to 60% or more and the effect of the removal is obvioused very good. However，comparing with the Fenton oxidation process，the pHotocatalytic oxidation process is still inadequate. The Advanced oxidation process in oxidative decomposition seems that the ?OH is the main material of the removal of a small molecule carboxylic，the ability to generate ?OH is one of the key points with the evolution of the removal ability of an advanced oxidation process. Photocatalytic oxidation proces