以TiO2-SiO2为载体的磷化镍催化剂加氢脱氮反应毕业论文.docxVIP

以TiO2-SiO2为载体的磷化镍催化剂加氢脱氮反应摘要近年来，石油馏分脱氮的问题受到越来越多的重视。氮含量高会导致燃料质量下降，柴油十六烷值降低，喷气燃料烟点增高及污染严重等问题。本文采用改进的溶胶-凝胶法制备了TiO2-SiO2复合载体，制备了不同Ti/Si配比的复合载体。考察了复合载体的制备条件对催化剂性能的影响。实验结果表明，复合载体的最优制备条件为： nTi/nSi为1:2，Ni2P负载量25%时，喹啉转化率为98%。在固定床反应器上，以最佳催化体系对模拟原料进行工艺条件的优化，采用程序升温法对其进行还原。考察催化剂不同反应温度、压力、进料体积空速、氢油比及原料中硫含量对催化剂加氢脱氮性能的影响。最佳工艺条件为：反应温度360℃，压力3.0 MPa , 空速为3h-1，氢油比500/1。关键词：改进的溶胶-凝胶法；复合载体；深度加氢脱氮；磷化钼ABSTRACTRecently, nitrogen saturation in distillate fractions has receivedconsiderable attention. A high nitrogen content is associated with poorfuel quality, giving a low cetane number in diesel fuel and a high smokepoint in jet fuel, and other environmental problems. In this paper TiO2-SiO2 mixed oxides with different molarratio of Ti、Si have been prepared by improved solgel method. Influenceof preparation condition ofthe molar ratio of Ti、Sion catalytic performance were investigated. The result of experimentindicated that optimalconditions for supporter were: nTi/nSi =1:2, quinoline transformation rate of 98 On the fixed-bed reactor, the technological conditions of modelfeedstock dydrotreating have been optimized, andcatalysts werereduction bytemperature -programmed method. The influence on thehydrodearomatics was investigated of reaction conditions at reactiontemperature, hydrogen pressure, liquid hourly spacevelocity，V(H2)/Voiland S content. And theresult also shows that optimum craftwork condition are: reactiontemperature 360 ℃, reaction pressure3.0 MPa , and LHSV 500/1.KEYWORDS:Improved sol-gelmethod;Noble metal catalyst;Depth hydrodenitrogenation；Molybdenumphosphides目录1前言31.1柴油中的氮化物及加氢脱氮机理31.1.1柴油中的氮化物31.1.2加氢脱氮（HDN）机理31.2新型加氢脱氮催化剂的活性组分31.3载体和助催化剂31.4加氢脱氮催化剂复合载体制备方法的研究31.4.1 浸渍法31.4.2沉淀法31.4.3 溶胶-凝胶法31.5 溶胶-凝胶（Sol-Gel）法31.5.1 溶胶-凝胶法工艺简介31.5.2 溶胶-凝胶法的基本原理31.5.3 溶胶-凝胶法的优点31.3选题意义32 实验部分错误！未定义书签。2.1 实验方案32.2实验试剂与仪器32.3 Ni2P/ TiO2- SiO2催化剂的制备错误！未定义书签。2.3.1 TiO2- SiO2复合载体的制备错误！未定义书签。2.4.2 活性组分的负载错误！未定义书签。2.5实验装置及实验步骤错误！未定义书签。2.5.1实验装置32.5.2实验步骤33结果与讨论33.1制备条件对喹啉转化率的影响33.1.1不同配比复合载体对催化剂脱氮活