水性丙烯酸树脂的合成与研究.doc

湖南化工职业技术学院 毕业论文 论文题目：水性环氧丙烯酸树脂的合成 指导教师姓名：刘宏 论文作者：段海波 专业：精细化学品生产技术 2013年12月 水性环氧丙烯酸树脂的合成 摘要：以双酚A型环氧树脂(E-44)为基础树脂、丙烯酸(AA)为改性剂,合成了溶剂型环氧丙烯酸树脂(EA),探讨了合成工艺条件(反应温度、反应时间、催化剂和阻聚剂用量)对AA转化率的影响.在此基础上,通过顺丁烯二酸酐(MA)与EA上的羟基反应,在EA上引入了羧基亲水性基团,制备了水性环氧丙烯酸树脂(EB).结果表明:当反应温度为95e、反应时间为415h、催化剂和阻聚剂用量分别为115%和01075% (与E-44的质量比)时,AA的转化率为98127%. EB合成的最优工艺条件为:反应温度80e,反应时间115h.采用傅里叶红外光谱分别对中间产物EA和目的产物EB进行结构表征,进一步证实AA与E-44开环酯化生成了EA,MA与EA上的羟基发生酯化反应生成了EB. 关键词：丙烯酸树脂；水性；合成 Synthesis ofW aterborne Epoxy Acrylate Xiao Xin-yan Hao Cai-cheng (School ofChemistry and ChemicalEngineering, South China University ofTechnology, Guangzhou 510640, Guangdong, China)Abstract:By usingbisphenol-A epoxy resin (E-44) as the basic resin and acrylic acid (AA) as themodifier, sol-vent-based epoxy acrylate (EA) was synthesized, and the effects of reaction temperature, reaction time, catalystcontentand inhibitor contenton theAA conversion were discussed. Afterwards, waterborne epoxy acrylate (EB)was synthesized via the reaction ofhydrophilic carboxy groups inmaleic anhydride (MA) with the hydroxylgroupsin EA. The results indicate tha,t when the mass ratios of the catalyst and the inhibitor to E-44 are respectively115% and 01075%, the polymerization results in aAA conversion up to 98127% at95efor415h; and that theoptimal temperature and time for EB synthesis are respectively 80eand 115 h. It is also demonstrated by theFT-IR spectra ofEA and EB that the formation ofEA is due to the ring-opening esterification ofAA with E-44,while thatofEB is due to the esterification ofMA with the hydroxyl groups in EA.Key words:bisphenol-A epoxy resin; acrylic acidmonomer; maleic anhydride; waterborne epoxy acrylate  目 录 序言………………………………………………………………………………………6 第1章 文献综述……………………………………………………………………7 1.1丙烯酸树脂发展概况………………………………………………………………7 1.2 水性丙烯酸树脂的分类…………………………………………………………8 1.3水性丙烯酸树脂的制备方法 ……………………………………………………9 1.3.1溶液聚合法………………………………………………………………9 1.3.2乳液聚合法………………………………………………………………11 1.4国内外在该领域的研究状况与分析 ……………………………………………12 1.4.1水性树