冷冻预处理对剩余污泥性质的影响研究.docVIP

冷冻预处理对剩余污泥性质的影响研究 胡凯赵庆良邱微（哈尔滨工业大学 市政环境工程学院，黑龙江 哈尔滨150090） 摘要：为了提高污泥有机物溶出率采用冻/技术污水厂剩余污泥，考查了冷冻时间对污泥理化特性的影响。结果表明，冻/处理可以破解污泥，将固体物质转化为液相成分。随着冷冻时间的增加，污泥pH值下降SCOD和碱度上升冷冻污泥的SS和 VSS值与冷冻时间相关。粒径分布和微观结构证了污泥絮体。与混合污泥相比，剩余污泥粒径分布的变化更加显著。剩余污泥和混合污泥经过72h/3h）处理，污泥物理特性。关键词：冷冻；污泥；；污泥破解Freeze/thaw Pre-treatment on Sewage Sludge Characterization HU Kai, ZHAO Qing-liang, QIU Wei (School of Municipal Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China) Abstract: In order to solubilize solid organic matter, which facilitated subsequent treatment process, freeze/thaw process was adopted as a waste activated sludge pre-treatment. Effect of freezing time on sludge characteristics was investigated. Results showed that freeze/thaw treatment could achieve sludge disintegration by transfering organic matter from solid phase into aqueous phase. Sludge pH decreased with an increasing freezing time, along with SCOD and alkalinity increment. Correlation analysis showed that SS and VSS were dependent of freezing time. Destruction of sludge floc was confirmed by particle size distribution and sludge microphotograph. A dramatic change regarding waste activated sludge in particle size distribution was observed in contrast with mixed sludge. Improvement of sludge solubilization and changes of physical properties were attained in freeze/thaw (72h/3h) treated sludge. Key words: freeze/thaw; sewage sludge; particle size distribution; floc structure; sludge disintegration 1 前言 []。冻/融处理作为一种有效的污泥调理手段，已经被证实能够改善污泥的脱水性能，使污泥颗粒结构更加紧密，同时还可以减少结合水含量[]。与机械法需要大量能耗和化学法需要添加化学药剂相比，冻/融处理的冷冻过程可自发进行（尤其适合于寒冷地区或者冬季气候），工艺简单，不需要使用大量聚合物，运行费用可大大降低。 目前有关冻/融处理技术集中在污泥絮体的固液分离特性研究方面，而对污泥破解和有机物溶出、冷冻后污泥的化学成分变化的研究还相对较少。有研究表明，冻/融预处理可以显著增加活性污泥上清液的BOD和COD[]。冻/融预处理不仅可以作为污泥调理的方法，也可以同时实现污泥破解，加速后续的厌氧消化进程等。基于此目的，本研究考查了-18 ℃下不同冷冻时间，剩余污泥和混合污泥的化学与物理性质的变化情况，以期为冻/融处理技术的应用提供技术参考。 2 实验材料与方法 2.1 污泥特性 实验所用的初沉污泥和剩余污泥分别取自哈尔滨某城市污水厂初次沉淀池和二沉池回流泵房。由于含水率较高，污泥静沉24h后，去除上清液，使其含水率至97%左右，贮存在4℃冰箱中备用。混合污泥的制备按照体积比1:4将初沉污泥和剩余污泥混合均匀。剩余污泥和混合污泥的理化性质