聚丙烯生产中原料丙烯的精制硕士论文.docVIP

XX大学 工程硕士专业学位论文 论文题目： 聚丙烯 2012年 4 月 10 日 Thesis for the Graduate Candidate Test Polypropylene raw material production of propylene refined Candidate: Li Xueshuang Tutor: Lv Chunsheng Field: Chemical Engineering Date of oral examination: 10th Apr.2012 University: Northeast Petroleum University  学位论文独创性声明 学位论文使用授权声明 聚丙烯生产中原料丙烯的精制 摘　要 本课题所依据的是以四万吨/年聚丙烯生产过程中的丙烯精制工艺装置为设计原型。原料丙烯的主要来源以炼厂气(主要为重油流化催化裂化分离后得到的丙烯)为主，成本较低且资源丰富，杂质含量较高，这些有害的杂质主要有炔烃、二烯烃、水、O2、CO、CO2、S和As等。传统的气体分离精馏装置可使乙烷、乙烯、丙烷、炔烃和二烯烃等杂质含量符合高效催化剂聚合时的要求。而丙烯中的硫（尤其是COS)、CO、CO2、H2O、O2和砷等杂质含量未能达到丙烯聚合级要求，因此需要对丙烯原料进行一系列的精制加工处理。 本课题研究了原料丙烯中含杂质含量对聚合反应以及催化剂的影响，根据原料所含杂质情况，有针对性的设置脱水、脱氧、脱硫和脱砷等精制工序脱除相应的杂质，提高精制丙烯的质量，降低产品物耗，提高产品质量关键词：；；；Polypropylene raw material production of propylene refined Abstract This topic is based on the forty thousand tons/year polypropylene production process of propylene refining process for design prototype device. The main source of raw material propylene in refinery gas (mainly As the commercial FCC separation later got propylene) primarily, low cost and rich resources, and impurity content is higher, the harmful impurities mainly has GuiTing, two olefins, water, O2, CO and CO2, S and As, etc. The traditional gas separation rectification device can make ethane, ethylene, propane, GuiTing and two alkenes etc with impurity content high-effective catalyst polymerization of requirements. And propylene of sulphur (especially COS), CO and CO2 and H2O, O2 and as impurity content failed to achieve propylene polymerization level requirement, so need to conduct a series of propylene raw materials refined processing. This topic research the raw material of propylene with impurity content on the influence of catalyst polymerization and, according to the raw material contains impurities, targeted set dehydration, deoxidization, desulfurization and take off as refined process corresponding impurity removal, improve the quality of the refined propylene, reduce the consump