聚乳酸高效抗氧剂及其热氧稳定作用研究.docVIP

  聚乳酸高效抗氧剂及其热氧稳定作用研究# 赵晓文，冯飞，叶林** （高分子材料工程国家重点实验室，四川大学高分子研究所，成都 610065） 5 10 15 20 摘要：本文针对 PLA 在加工和使用过程中易发生热氧降解造成相对分子质量降低、力学性能 下降和发黄发脆的问题，研究其高效热氧稳定体系，通过对其热稳定作用研究，有效提高 PLA 热氧稳定性能。结果表明，相对于一元、二元抗氧体系，本文所设计的三元抗氧体系 Irganox1010/Irgafox168/TR 对 PLA 具有较低的热失重率和热失重速率，表现出较好的热氧 稳定效果；少量的三元抗氧剂对 PLA 即有明显的热氧稳定作用，使其热失重率和热失重速率 较低，平衡扭矩较高，有效阻碍 PLA 在热、氧、应力作用下分子量的降低，其最佳用量范围 为 0.1～0.2wt%；与纯 PLA 相比，加有三元抗氧体系的 PLA 经长期热氧老化后可保持较高的 分子量，且黄度最浅，具有较高的抗氧化着色能力；抗氧剂具有异相成核作用，使 PLA 球晶 细化，结晶度增大，在长期热氧老化过程中，PLA 球晶尺寸增大，结晶更完善，结晶度显著 提高，这是由于 PLA 无定型区分子链断裂降解，从而使其结晶区的比例增加的结果；老化后 纯 PLA 结晶度反而略高于稳定化 PLA，表明纯 PLA 非晶区的降解较为严重。 关键词：聚乳酸（PLA）；抗氧剂；热稳定性 中图分类号：TQ322.3 Study on the High Efficiency Antioxidant of Poly (lactic acid) and its thermal stabilization effect ZHAO Xiaowen, FENG Fei, YE Lin (State Key Laboratory of Polymer Materials Engineering of China, Polymer Research Institute of Sichuan University, Chengdu 610065) 25 Abstract: For the problem of thermal oxidative degradation of PLA during processing and application, resulting in the reduction of the relative molecule weight and mechanical properties of PLA, brittleness and yellowing, this work aimed to develop the high efficiency thermal stabilizing system and improve the thermal stability of PLA by studying the thermal stabilizing effect of the system. Through the investigation of the thermal stabilization effect of various antioxidant systems 30 35 40 45 with the same content of the antioxidant or the same of the main antioxidant on PLA, the ternary antioxidant system of PLA/Irganox1010/Irgafox168/TR had lower isothermal weight loss and the thermal degradation rate, and exhibited better stabilizing effect on PLA, compared with the mono antioxidant system and the binary antioxidant system. Very small dosage of the ternary antioxidant system presented high thermal stabilization effect on PLA, which had relatively low isothermal weight loss and degradation rate, and relatively high balance torque, and the molecular degradation of PLA under heat, oxygen and