小分子液体的高温高压布里渊散射研究.docVIP

  小分子液体的高温高压布里渊散射研究# 马春丽1，武晓鑫1，黄凤仙1，李敏2，王晓霞1，周强1，李芳菲1，崔啟良1** （1. 吉林大学超硬材料国家重点实验室，长春 130012； 5 10 15 20 25 30 35 40 2. 西安科技大学理学院，西安 710054） 摘要：利用金刚石对顶砧技术，采用 180 度背向散射和 60 度前向对称散射两种几何配置, 对水、氨、二水合氨和甲烷等含氢小分子液体进行了高温高压布里渊散射研究，计算了它们 在室温(296 K)和高温(410 K)下的声速，比较了不同小分子液体中的声速及绝热体弹模量随 着压力的变化关系。在等温条件下，各体系中声速随着压力的增加逐渐增加；在相同温度下， 甲烷液体的声速随着压力增加的速率明显高于水、氨、及二水合氨液体；在相同的温度和压 力条件下，水、氨、及二水合氨液体的体弹模量明显高于甲烷液体的体弹模量，这表明氢键 的存在对于小分子液体弹性具有较大影响。二水合氨的体弹模量斜率在 1.5 GPa 左右发生改 变，表明液体结构可能发生了改变，并分析了氢键对该体系弹性性质的影响。这些研究，将 有助于加深我们对其他含氢小分子液体中压力和温度诱导的分子结构变化的理解。 关键词：高温高压；布里渊散射；声速；绝热体弹模量；小分子液体 中图分类号：O469 Brillouin Scattering Study on Molecular Liquid under High Pressure and High Temperature Conditions MA Chunli1, WU Xiaoxin1, HUANG Fengxian1, LI Min2, WANG Xiaoxia1, ZHOU Qiang1, LI Fangfei1, CUI Qiliang1 (1. Key State Laboratory of Superhard Materials, Jilin University, ChangChun 130012; 2. College of Science, Xian University of Science and Technology, Xian 710054) Abstract: High-pressure and high-temperature Brillouin scattering studies have been performed on molecular liquids, including water (H2O), ammonia (NH3), ammonia dihydrate (NH3·2H2O) and methane (CH4). The acoustic velocity and adiabatic bulk modulus have been determined from measured Brillouin frequency shifts in both 180° and 60° scattering geometries under pressure up to freezing point, along room temperature (296 K) and high temperature (410 K) isotherms. The acoustic velocities increase smoothly with increasing pressure, methane possess the highest velocity increasement and lowest adiabatic bulk modulus under similar pressure and temperature, indicating the hydrogen bond impact on elastic prosperities in these liquids. A change in the slope of pressure dependence of the bulk modulus in ammonia dihydrate liquid was observed around 1.5 GPa, suggesting a possible structure change, this study improves our understanding of the pressure- and temperature-induced molecular structure changes in other molecular liquid systems. Keywords: High temperatur