氧气比对锯末流化床气化焦油性质的影响比.docVIP

  氧气比对锯末流化床气化焦油性质的 影响比# 秦育红，冯杰，李文英** 5 10 15 20 25 30 35 40 （太原理工大学煤科学与技术教育部和山西省重点实验室，煤科学与技术省部共建国家重点 实验室培育基地，太原 030024） 摘要：焦油的形成是影响生物质气化技术商业化运作的瓶颈，氧气比(OR)是影响焦油形成和 裂解的主要因素。本研究以樟子松锯末为原料，以氧气量为唯一的变化因素在喷动流化床中 900?C 下进行气化实验。利用凝胶渗透色谱结合二极管阵列检测器(GPC-PDA)以及气质联用 分析技术(GC-MS)对不同氧气量下气化所得到的焦油性质进行了分析。结果表明：气化焦油 都具有芳香特性，单一的改变氧气量不会改变气化焦油的分子量及其分布，焦油中主要化合 物结构特征也没有改变，改变的是不同化合物的相对含量，焦油的结构主要以带/不带支链 的芳香族化合物以及含氧的极性小分子化合物为主。只改变气化过程中氧气的量只能使焦油 的产率降低，并不能使全部焦油裂解。 关键词：气化；锯末；焦油；氧气比例 中图分类号：TK6 Effect of Oxygen Ratio on Characterization of Sawdust Gasification Tar in the Fludized Bed Qin Yuhong, Feng Jie, Li Wenying (Key Laboratory of Coal Science and Technology (Taiyuan University of Technology), Ministry of Education and Shanxi Province, Training Base of State Key Laboratory of Coal Science and Technology Jointly Constructed by Shanxi province and Ministry of Science and Technology, TaiYuan 030024) Abstract: The formation of tar is the bottleneck of commerical development during the biomass gasification. The oxygen ratio (OR) is the main impact on the tar formation and cracking. Pinus sawdust is as raw material was gasified in a spout fludized bed at 900?C. The oxygen ratio is the only variable. The property of tar was researched by using Gel permeation chromatography coupled with photodiode array detector(GPC-PDA) and Gas chromatography-Mass Spectrometry (GC-MS) analytical techniques. The gasified tar showed aromatic character. The molecular mass and molecular mass distribution were unchanged with the increasing OR and the conjugated structure of tar did not change too. But the relative quantity of compounds changed. The main compounds in tar were aromatic compounds with or without sidechains and oxygen-containing polar small molecuar compounds. The tar yield decreased, while tar will not crack thoroughly when the variable is only oxygen ratio. Keywords: Gasification; Sawdust; Tar; Oxygen Ratio 0 引言 在生物质气化技术的商业化运作中，当量比（ER）的定义是对于一定的进料量，实际 通入氧气（空气）的质量与完全燃烧所需要氧气（空气）质量的比率，它是与气化温度紧密 相关的一个参数。适度的增加空气