多壁碳纳米管纯化及其表面含氧基团表征.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 3080 A cta Phys. Chim. Sin., 2010, 26(11) ：3080-3086 November [Article] 多壁碳纳米管的纯化及其表面含氧基团的表征 金梅 李海燕 林国栋 张鸿斌* ( 门大学化学化工学院, 固体表面物理化学国家重点实验室, 醇醚酯化工清洁生产国家工程实验室, 福建厦门 361005) 摘要： 用兼具酸性和氧化性的HNO3 水溶液可方便地除去残留在原生态多壁碳纳米管(CNT)上的Ni MgO 催 化剂组分, 同时在其表面产生某些含氧官能团, 使原生态多壁碳纳米管的疏水性表面变为亲水性表面. 采用 Boehm 中和滴定法以及X 射线衍射(XRD) 、热脱附谱(TPD) 、傅里叶变 红外(FTIR)光谱和X 射线光电子能谱 (XPS)等技术对HNO3 处理过的多壁碳纳米管的相组成和表面含氧官能团进行测量和表征. 结果表明: 所生成表 面含氧官能团的总量以经7.0 mol ·L-1 硝酸378 K 处理24 h 的CNT 为最高; 3 种主要表面含氧官能团的含量高 低顺序为, 羧基 内酯型羧基酚型羟基. 关键词： 多壁碳纳米管; 纯化; 表面含氧官能团; 表面修饰 中图分类号： O647 Purification of Multiwalled Carbon Nanotubes and Characterization of Their Oxygen Containing Surface Groups ZHOU Jin Mei LI Hai Yan LIN Guo Dong ZHANG Hong Bin* (College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry f or Solid Surf aces, National Engineering Laboratory f or Green Chemical Productions of A lcohols Ethers Esters, Xiamen University, X iamen 361005, Fuj ian Province, P. R. China) Abstract ： We conveniently removed the Ni MgO catalyst components from an as grown multiwalled carbon nanotube (CNT) using an aqueous HNO3 solution with strong acidity and oxidizability as a purifying reagent . Some oxygen containing surface groups were generated at the CNT surface, which converted the hydrophobic surface into a hydrophilic surface. The phase composition and the oxygen containing surface groups of the CNTs treated by nitric acid were determined and characterized using Bo