全钒液流电池用PTFE-碳纳米管电极的性能.pdfVIP

第2 卷 第3 期 储 能 科 学 与 技 术 Vol.2 No.3 2013 年5 月 Energy Storage Science and Technology May 2013 研究及进展 全钒液流电池用 PTFE-碳纳米管电极的性能 李丹丹，褚有群，李雯雯，马淳安 （浙江工业大学化学工程与材料学院，浙江杭州 310014 ） 摘 要：以聚四氟乙烯（PTFE ）为黏结剂制备了不同组分的石墨粉（GP ）和多壁碳纳米管（MWCNT ）复合电 极，采用恒电位阶跃、循环伏安、电化学阻抗谱及恒电流充放电等方法系统考察了 GP-MWCNT 复合电极在全 钒液流电池（VRFB ）体系中的电化学性能。实验结果表明：复合电极中MWCNT 含量的增加有利于VRFB 正、 负极反应的进行，纯MWCNT 电极表现出最优的电化学性能；以纯MWCNT 电极为正、负极构建的VRFB 电池 在 30 mA/cm2 的恒电流充放电条件下表现出了良好的稳定性和电化学性能，电流效率、电压效率和能量效率分 别为96% 、87%和84%。 关键词：全钒液流电池；石墨；碳纳米管；复合电极；电化学性能 doi：10.3969/j.issn.2095-4239.2013.03.007 中图分类号：TM 911；TB 33 文献标志码：A 文章编号：2095-4239 （2013 ）03-227-06 Characteristics of graphite based composite electrodes containing carbon nanotubes for vanadium redox flow batteries LI Dandan ，CHU Youqun，LI Wenwen ，MA Chunan （College of Chemical Engineering and Materials Science ，Zhejiang University of Technology ，Hangzhou 310014 ，Zhejiang ，China ） Abstract ：Graphite (GP) based composite electrodes containing multi-walled carbon nanotube (MWCNT) were prepared for vanadium redox flow batteries (VRFB) using polytetrafluoroethylene (PTFE) as binding agent. Electrochemical performance of the GP-MWCNT composite electrodes was characterized by chronoamperometry, cyclic voltammetry and electrochemical impedance spectroscopy. The results showed that both positive and negative electrode reactions of VRFB benefited from the use of more MWCNT in the composite electrode, and the best electrochemical performance was obtained with pure MWCNT electrode. A VRFB was ther