拉曼光谱应用介绍.pptVIP

拉曼光谱的应用 拉曼应用 拉曼应用 应用市场分析 司法科学-文检 司法科学-文检 司法科学-理化检验 司法科学-文检 司法科学-文检 780 nm laser 10 sec exposure time 2 exposures 司法科学-理化分析 785 nm laser 10 seconds collection 司法科学-理化 司法科学-卖点 文物考古-技术推广 碳材料拉曼光谱 Diamond sp3 bonded carbon Graphite sp2 bonded carbon Sheet of aromatic rings Fullerenes Hollow carbon spheres Diamond-like Carbon (DLC) coatings Amorphous Carbon Properties similar to Diamond Sometimes hydrogenated Different forms sometimes called polymorphs More accurately allotropes 碳材料 Graphene Single layers from Graphite structure Graphene nanoribbons (GNR) roll up to form nanotubes SW-CNT MW-CNT Carbon nanowalls Walled graphene structures 碳材料 碳材料 RBM波段（呼吸模) 表征单壁碳管管径 间接表征手性与电特性 对激发波长很敏感 多壁碳管没有这个峰 碳材料 G Bands (Tangential or Graphite bands) Centered around 1580 cm-1 Represent C-C stretching mode Good for determining electrical property (metallic or semiconducting) Broadened G-band indicates metallic Nonresonant 碳材料 D bands (Diamond or Defect bands) Centered around 1335 cm-1 Indicate defects in SW-CNTs Prominent in MW-CNTs 碳材料拉曼光谱 Raman can be used to compare and contrast nanotubes for the purposes of fine-tuning a synthesis process 碳材料 two carbon peaks graphitic “G” disordered carbon “D” correlations D/G area/intensity ratio correlates with wear resistance G band area and intensity correlates with thickness G band positioncorrelates with wear resistance background slopecorrelates with hydrogen content Raman band at 2300 cm-1 correlates with nitrogen content 碳材料 碳材料-卖点 药学-晶形鉴别 药学-晶形鉴别 药学-晶形鉴别 药物-晶形鉴定 多晶形药物筛选 多孔板 96 well, 384 well, and 1536 well plates TQ Analyst 定量分析方法 DXR 的解偏激光器保证了药物的拉曼光谱不受激光偏振影响 药学-低波数信息 Spectrum of Amino Acid – Cystine Low frequency bands in Raman Shift Raman analytical signal occurs near wavelength of the laser where easily sensed by the detector Far IR equipment not required 药学-卖点 掺杂对拉曼光谱影响 结晶度 聚合物生长 环境科学：温室与燃烧物气体对建筑材料的腐蚀 环境科学-温室与燃烧物气体对建筑材料的腐蚀研究 市场分析 积累潜在客户 CNT Applications require flexible sampling methods Macro Measurements: Physical properti