毕业论文--PVCCa,Zn-水滑石复合热稳定剂体系的流变性研究.doc

唐山师范学院本科毕业论文 题 目 PVC流变性研究 唐山师范学院化学系 2013年月 郑 重 声 明 本人的毕业论文是在指导教师 的指导下独立撰写并完成的。毕业论文如有剽窃、抄袭、造假等违反学术道德、学术规范和侵权行为，本人愿意承担由此产生的各种后果，直至法律责任；并可以通过网络接受公众的查询。特此郑重声明。 毕业论文作者： 年 月 日 小份量的ACR使PVC物料的塑化时间明显缩短,3份以上时,对塑化时间影响不明显Abstract Ca-Zn-hydrotalcite thermal stabilizer was environmental-friendly material which has excellent thermal properties. The effect of CPE, ACR KM310, ACR401 and PE wax on the rheological properties of PVC/Ca-Zn-hydrotalcite thermal stabilizer was investigated using torque rheometer.In the processing of PVC product ,we can be based on the rheological properties of PVC to adjust the formula,ensure the stability of product production.The results show that the torque of PVC/Ca-Zn-hydrotalcite thermal stabilizer increased with CPE or ACR KM310 content,but the plasticizing time of PVC becomes short with increasing of CPE or ACR KM310 proportion. ACR401 exhibited great effect on the rheological properties of CPE recipe but little effect on the rheological properties of ACR KM310 recipe,The plasticizing time of PVC will be shortened obviously with a small amount ACR401 added,and the effect would be weakened when the addition of ACR401 is more than 3 phr . PE wax acted as internal lubrication when PE wax content was lower to 1 phr, but acted as internal and external lubrication with increasing PE wax content. Key words PVC thermal stabilizer Rheological properties plasticizing time PVC/Ca,Zn-水滑石复合热稳定剂体系的流变性研究 2 实验部分试剂主要试剂及产地列于表1。PVC/钙-锌-水滑石复合热稳定剂体系物料配方钙-锌-水滑石复合热稳定剂PVC/钙-锌-水滑石复合热稳定剂体系物料配方 钙-锌-水滑石复合热稳定剂 2.5流变性能测试 PVC/钙-锌-水滑石复合热稳定剂体系物料配方如表1所示。按表1称取物料，机械混合30 min，混料温度70 ℃。采用转矩流变仪（RM-200A，哈尔滨哈普仪器有限公司）测定PVC/钙-锌-水滑石复合热稳定剂体系的流变性能，测试条件：温度180℃，转速为30 rpm，每次流变实验物料重量为64 g。 3 结果与讨论 3.1加料量对PVC体系流变性能的影响 原料的加入量过多过少，都会对实验造成不小的误差。加料量太少，压杆没有压在干混料上，导致塑化时间过长，扭矩过小；加料量过多，塑化时间明显缩短，扭矩过大。因此需要准确地确立加料量。如表2所示，PVC塑化时间过长会导致分解，塑化时间过短导致未完全熔融，在挤出成型工艺中均导致挤出产品不合格。对比各加料质量，塑化时间应根据仪器的参数来初步确定，最大扭矩不宜过大，如果过大会导致耗能较大，平衡扭矩应适中。综上所