纯镁表面硬脂酸自组装膜处理工艺及其性能.pdfVIP

中国科技论文在线 纯镁表面硬脂酸自组装膜处理工艺及其 性能# 乔丽英，高家诚，王勇，谢奉妤，胡德* 5 （重庆大学材料科学与工程学院，重庆 400044） 摘要：为改善镁金属在生理环境中的腐蚀行为与生物活性，采用硬脂酸对纯镁进行表面有机 自组装膜改性研究。有机改性前，先对试样进行3 种不同的前处理：酸碱处理、热处理和碱 热处理；通过正交试验优选最佳的预处理方法、硬脂酸溶液浓度和处理时间。对不同预处理 和硬脂酸改性后的试样进行电化学行为分析, 并对最佳工艺改性前后的试样进行了静态水 10 接触角的测量及仿生溶液(SBF)浸泡试验分析，跟踪测试 SBF 溶液的 pH 值及镁离子浓度变 化，利用扫描电子显微镜（SEM-EDS ）观察SBF 中浸泡后的试样表面形貌，并分析其表面 成分。试验结果表明：以热处理为前预理方式，在 0.5 mol/L 硬脂酸乙醇溶液中浸泡 1.5h 的 试样耐蚀性最优，该膜层改变了材料表面的润湿性，使其与水的接触角增大，并明显降低了 材料的腐蚀速度及提高了其生物活性。 15 关键词：自组装；纯镁；硬脂酸；工艺；腐蚀；生物活性 中图分类号：TG146; TG178 Technology and Performance Study of Stearic Acid SAMs on Pure Magnesium 20 Qiao Liying, Gao Jiacheng, Wang Yong, Xie Fengyu, Hu De (College of Materials Science and Engineering, Chongqing University, ChongQing 400044) Abstract: The surface-treatment of self-assembled monolayer (SAMs) of stearic acid on pure magnesium was studied to improve the bioactivity and corrosion resistance of pure Mg. Three pre-treatment methods (HCl-NaOH treatment, alkali-heat treatment and heat treatment) were used 25 before SAMs treatment carried out in stearic acid. The orthogonal test was performed to select the best pre-treatment method, concentration of solution and soaking time. The electrochemical properties of samples with different pre-treatment were tested; the water contact angles of samples with and without SAMs treatment were studied; and samples also were immersed in si