废线路板非金属粉末HZSM-5催化热解三相产物分析.pdfVIP

中国科技论文在线 废线路板非金属粉末HZSM-5 催化热解 三相产物分析 杨帆，孙水裕，李神勇，王逸，伍家麒，刘敬勇 (广东工业大学环境科学与工程学院，广州 510006) 摘要：通过利用 HZSM-5 分子筛作为催化剂对废线路板非金属粉末进行催化热解试验，对 加入和不加入催化剂两种情况下热解油、热解渣、热解气的成分进行分析和比较。实验结果 表明：在加入HZSM-5 后，废线路板非金属粉末热解的三相产物成分品质均得到较大改善。 其中，固相产物含量较未加入催化剂热解时减少，液相产物含量增加；热解油中轻组分含量 上升，苯酚质量分数达到38.43% ，含溴有机物质量分数为2%；废线路板固体渣质量分数为 58.67% ，固体渣中可挥发成分的质量分数为3.53%；热解尾气中二氧化碳体积分数为87.52%， 不可冷凝有机气体含量约占气体总量 10%。实验研究结果为HZSM-5 催化热解废线路板的 工业化利用提供理论基础。 关键词：资源化利用；废线路板；热解；催化剂；HZSM-5 中图分类号：X783.2 文献标识码：A Characterization of pyrolysis of products from waste printed circuit boards (WPCB) pyrolysis catalyzed by HZSM-5 Yang Fan, Sun Shuiyu, Li Shenyong, Wang Yi, Wu Jiaqi, Liu Jingyong (School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China) Abstract: In order to evaluate the catalytic performance of HZSM-5 in the pyrolysis of waste printed circuit boards (WPCB), the pyrolysis of non-metal powder separated from WPCB was carried out using HZSM-5 as catalyst. Then the three-phase products from the catalytic pyrolysis process were analyzed and compared with that without HZSM-5 catalysis. The results showed that the yields of liquid-phase products increased. The mass fraction of valuable component in pyrolysis oil like phenol could reach 38.43%. The proportion of brominated organics was 2%; the solid residue from catalytic pyrolysis was 58.67%, which was less than that without the addition of HZSM-5; the pyrolysis gas consisted of 87.52% CO2 and less than 10% of organic components. The results indicated that the quality of the three-phase products was improved by the pyrolysis of WPCB non-metal powder catalyzed by HZSM-5. Our study also provides theoretical foundation for industrial application of catalytic py