基于truxene的星型对称与非对称有机光电功能分子研究.pdfVIP

中国科技论文在线 基于 truxene 的星型对称与非对称有机光电 功能分子研究# 王齐，袁茂森** 5 （西北农林科技大学理学院，陕西杨凌 712100 ） 摘要：功能化的星型有机分子由于其新颖的结构和独特的性质，已被广泛应用于有机光电材 料。其中三聚茚（truxene ）由于其具有三重对称性的刚性平面结构，在构筑星型分子方面具 有独到的优势而受到了特别的关注。本文以三聚茚为π扩展中心，分别在其端基的 2 ，7 ， 12-位被二苯胺基和2-噻吩乙炔基功能化，合成了一个对称和2 个非对称的星型分子，并对 10 它们的结构和光学性质进行了探索。被功能化后它们都表现出了优良的发光性能，随着π体 系的扩展，化合物的发光峰位逐渐发生红移，非对称化合物1.2 2–(2-噻吩乙炔基)-7,12- 二 (二苯胺基)-5,5 ΄,10,10 ΄,15,15 ΄-六乙基三聚茚（N2CS ）具有最长的发射波长和最高的量子产率。 关键词：有机化学；光学性质；结构；三聚茚 中图分类号：O625.15+9 15 Truxene-based star-shaped symmetrical and asymmetrical organic photoelectric molecules Wang Qi, Yuan Maosen (College of Science, Northwest AF University, ShanXi YangLing 712100) 20 Abstract: Functionalized organic star-shaped molecules have been widely applied as organic optoelectronic materials due to their fascinating structures and unique properties. Because of its C3-symmetrical rigid plane structure, truxene has been extensively focused in fabricating organic star-shaped molecules. In this paper, truxene was used as the π-expanded central core, and several symmetrical and asymmetrical organic conjugated molecules were synthesized through 25 replacing different dendron (diphenylamino and 2-thiophenylethynyl) at its three terminals. Their structures and photophysical properties were explored. Functionalized truxene derivatives possess excellent luminescent properties. With the extension of π-conjuagtion, the emission peaks of corresponding co