NbCl5氢还原制备金属铌粉的热力学模拟.pdfVIP

第 30 卷 第 6 期 北 京 科 技 大 学 学 报 Vol . 30 No. 6 2008 年 6 月 Journal of University of Science and Technology Beij ing Jun. 2008 NbCl5 氢还原制备金属铌粉的热力学模拟 曹战民　乔芝郁 　朱 　骏 　朱鸿民 北京科技大学冶金与生态工程学院 , 北京 100083 摘 　要 　基于过程模拟开发组件库 Simu Sage 开发了通过氢气还原氩气气氛中的 NbCl5 制备超细铌粉的热力学模拟程序 ,讨 ( ( ) ) ( ) ( ) 论了蒸发温度 、载气用量 Ar g 、还原反应温度 、H2 g 用量 、收集区温度等关键参数的影响. 研究表明:NbCl5 s 的蒸发率以 ( ) ( ) ( ) 及气相中NbCl5 g 的浓度取决于蒸发温度及氩气的用量 ;还原温度为 1 000 ℃时固相产物为 Nb s 单一相所需的最小 H2 g 用量为 20 mol/ 1 mol NbCl5 ;提高收集区温度有利于获得高纯度固相 Nb 粉产物. 关键词 　铌粉 ; 氢还原 ; 热力学模拟 ; 工艺参数 分类号 　T G 1464 Thermodyna mic simulation of hydrogen reduction of NbCl 5 to produce Nb metal powder CA O Zhan m in , QIA O Zhiy u , ZH U J un , ZH U Hong m in School of Metallurgical and Ecological Engineering , Univer sit y of Science and Technology Beijing , Beijing 100083 , China ABSTRACT 　A t hermodynamic simulation program for Nb powder production process by hydrogen reduction of NbCl5 in argon was develop ed by using Simu Sage Software , which is a component library used in t he developing of process simulation . The effect s of t he key p arameters such as evaporation temp erature , loading gas amount (Ar (g) ) , reduction temp erature , H2 (g) amount and collection temp erature were studied by t he simulation program . The result s show t hat t he evaporation rate of NbCl ( ) 5 s and t he content of (