新型钛硅分子筛hts-1催化环戊烯氧化.docVIP

新型钛硅分子筛HTS-1催化环戊烯氧化 摘 要：1,2-环氧环戊烷（CPEO）是无色油状液体，沸点是102℃，CPE）合成。新型钛硅分子筛HTS-1具有新颖空心构型。我国已经将HTS-1列为特种催化材料，并成功应用于具有自主知识产权的己内酰胺生产新工艺技术的开发。目前HTS-1的一个方法是利用钛硅分子筛为催化剂、双氧水为氧化剂实现丙烯、氯丙烯环氧化制环氧丙烷和环氧氯丙烷已在国内进入到试产阶段。HTS-1作催化剂，双氧水为氧化剂，研究由环己烯一步合成1,2-环氧环己烷。本课题探讨HTS-1在催化过氧化氢氧化环戊烯反应过程中各因素对体系中H2O2利用率的影响，以期得出合成1,2-环氧环戊烷最佳工艺条件，为医药、有机合成领域的实际应用提供材料支持，并拓展HTS-1在催化环氧化等领域的应用。 关键词：环戊烯 氧化剂 双氧水 新型分子筛 催化剂 Abstract：1，2-Epoxycyclopentane is a colorless oily liquid，boilling point is 105°C. It an important medicine and organic synthesis intermediates. It can be compounded by cyclopentene epoxidized synthesis. HTS-1 have a new titanium silicon molecular sieve. Our Country has regarded HTS-1 as special catalytic materials， and successfully applied to have independent intellectual property rights of caprolactam production new process technology development. At present， a method for preparation of a novel titanium silicate molecular sieve HTS-1 is the use of titanium silicalite molecular sieve as catalyst，hydrogen peroxide is oxidizer realization of propylene， chlorine oxidation of propylene to propylene oxide and epichlorohydrin， has in the country entered into trial production stage.Discussion on the issue of HTS-1 in the catalytic hydrogen peroxide oxidation of cyclopentene reaction process factors on the system H2O2 utilization effect，in order to obtain the synthesis of 1, 2 - Epoxy cyclopentane optimum conditions for the field of organic synthesis， pharmaceutical, a practical application in providing material support, and the expansion of HTS-1 in catalytic epoxidation and other fields application. Key word：Cyclopentene oxidizing agent hydrogen peroxide a novel molecular sieve catalyst 目录 一 实验药品及仪器 1 （一） 实验药品 1