Lewis酸掺杂聚苯胺的合成及应用设计论文.docVIP

安徽工业大学 毕业设计(论文)说明书 Lewis酸掺杂聚苯胺的合成及应用 高分子材料与工程专业周道军(069034035)指导教师万玉保副教授 ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ 装 ┊ ┊ ┊ ┊ ┊ 订 ┊ ┊ ┊ ┊ ┊ 线 ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ 摘要 以 Lewis酸掺杂聚苯胺为催化剂，乙酸和异戊醇为原料，酯化反应合成乙酸异戊 酯。通过正交实验法，对硫酸铜掺杂聚苯胺工艺条件即 Cu离子浓度及用量、掺杂 2+ 温度和掺杂时间，进行了优化，并对其进行电导率测定和 IR结构表征。CuSO4掺杂 聚苯胺为催化剂，考察了醇酸比、催化剂用量、反应时间和带水剂种类及用量对酯化 反应的影响。实验结果表明， CuSO4掺杂聚苯胺优化条件为 Cu浓度 1.5mol/L， 2+ nPANI:nLewis2:1，50℃下掺杂 48h。乙酸用量 0.02mol，醇酸摩尔比 1.2:1.0，催化剂用量 占反应物总质量的 4.0%，带水剂二甲苯 10.0mL，回流时间 4.0h，酯收率可达 90.6%。 所得产物易分离纯化，操作过程简单易行。CuSO4掺杂聚苯胺是酯化反应良好催化剂， 催化活性高，稳定性好。该催化剂具有成本低、使用寿命长和对环境友好的优点。 关键词：聚苯胺；掺杂；Lewis酸；乙酸异戊酯；酯化 共 25页 第 1页 安徽工业大学 毕业设计(论文)说明书 Abstract Isoamyl acetate from acetic acid and isoamyl alcohol using Lewis acid-doped polyaniline(PANI) as catalyst was prepared. Process conditions of CuSO4-doped ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ 装 ┊ ┊ ┊ ┊ ┊ 订 ┊ ┊ ┊ ┊ ┊ 线 ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ polyaniline such as concentration and amount of Cu , doping temperature and doping time 2+ were optimized by orthogonal experiments. The structure of the catalyst was characterized by IR spectroscopy, and the electrical conductivity of Lewis acid-doped polyaniline was measured. As concerning synthesis of isoamyl acetate, effects of catalyst dosage,molar ratio of isoamyl alcohol to acetic acid, reaction time, type and dosage of water entrainer on esterification rate were investigated. Preparing conditions of CuSO4-doped polyaniline were concentration of Cu 1.5mol/L, molar ratio of to Lewis acid 2:1, doping temperature 2+ 50℃ for 48h. Under the optimal conditions of molar ratio of isoamyl alcohol to acetic acid 1.2:1.0, mass fraction of catalyst in feed stock 4.0%, 10.0mL xylene as water entrainer, reaction time 4.0h, esterification rate is 90.6% in the presence of 0.02 mole acetic acid. Isoamyl acetate is easily separated from the reaction system and purified. The catalyst showed high catalytic activity and stability, and takes a