可渗透反应墙材料除氮实验研究.pdfVIP

中国环境科学 2013,33(S1) ：98~102 China Environmental Science 可渗透反应墙材料除氮实验研究 * 骆其金,谌建宇 ,黄荣新,庞志华,王振兴,罗 隽,林方敏 (环境保护部华南环境科学研究所,广东 广州 510655) 摘要：通过单因素的影响试验,讨论了进水初始 pH 值、进水硝酸盐初始浓度、反应时间及添加竹炭、二氧化锰等因素对可渗透反应墙(PRB) 材料铁屑去除总氮、硝酸盐量的影响.结果表明,改变进水初始 pH 值、进水硝酸盐初始浓度、反应时间等常规影响因素及竹炭的添加都不 能明显的提高单位质量铁屑对总氮、硝酸盐的去除量,但添加少量二氧化锰增加了单位铁屑去除总氮、硝酸盐的量,总氮的去除量由不 添加剂的 0.05mg/g 增加到 0.17mg/g,去除量是原来的 3 倍以上, 同时会减少氨氮的生成. 关键词：铁屑；硝酸盐；反硝化；催化剂 中图分类号：X52 文献标识码：A 文章编号：1000-6923(2013)S1-0098-05 * Nitrogen removal study of scrap iron in permeable reactive barriers. LUO Qi-jin, CHEN Jian-yu , HUANG Rong-xin, PANG Zhi-hua, WANG Zhen-xing, LUO Jun, LIN Fang-min (South China Institute of Environmental Sciences, Ministry of Environmental Protection of the People’s Republic of China, Guangzhou, 510655, China). China Environmental Science, 2013,33(S1)：98~102 Abstract ：This paper discussed effects of various factors on the reduction of total nitrogen and nitrate with scrap iron(materials of PRB)respectively through single-factor experiment. These factors include pH, nitrate concentration of influent, reaction time and addition of bamboo charcoals, or manganese dioxide. Results indicated that reduction of nitrate and total nitrogen remain similar with change of pH, nitrate concentration of influent, reaction time or addition of bamboo charcoals. Interestingly, the nitrate and total nitrogen reduction by per g scrap iron improved dramatically with the addition of manganese dioxide. When adding manganese dioxide to the reaction, total nitrogen reduction by scrap iron increases 3 fold from 0.05mg/g to 0.17mg/g and the production of ammonia decreases simultaneously. Key words ：scrap iron；nitrate ；denitrificat