两种释碳材料的制备及其性能研究.pdfVIP

中国环境科学 2012,32(11) ：1984~1990 China Environmental Science 两种释碳材料的制备及其性能研究 闫 续,许 柯,耿金菊,任洪强* (南京大学环境学院,污染控制与资源化研究国家重点实验室,江苏 南京 210046) 摘要：应用固定化技术制备了包埋淀粉的聚乙烯醇(PVA)释碳材料和海藻酸钠(SA)释碳材料,采用红外光谱和扫描电镜对其物化特性进行 分析,研究了二者的释碳性能以及作为碳源对硝态氮的去除效果.结果表明,PVA 释碳材料中淀粉混合较好,释碳过程满足二级动力学方程, 单位质量材料释放的饱和 COD 达到 99.60mg/(g·L).在温度为 18~22℃,pH7.2~8.0,硝态氮浓度为 35mg/L 的条件下,PVA 释碳材料的平均反 3 3 硝化速率为 18.5g/(m ·d),SA 释碳材料的平均反硝化速率为 15.5g/(m ·d),在稳定运行 15d 后,出水硝态氮浓度逐渐升高,脱氮效果开始下降. 关键词：反硝化；释碳材料；淀粉；聚乙烯醇；海藻酸钠；微生物载体 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2012)11-1984-07 Preparation and properties of two kinds of carbon releasing material. YAN Xu, XU Ke, GENG Jin-ju, REN Hong-qiang* (State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210046, China). China Environmental Science, 2012,32(11)：1984~1990 Abstract ：Two kinds of carbon releasing material containing starch were prepared with PVA (polyvinyl alcohol) and SA (sodium alginate) by immobilization technique. Fourier transform infrared spectroscopy (FTIR) was used to investigate the changes in characteristics of the two materials. Their surface and inside morphology were observed by scanning electron microscopy (SEM). Moreover, their COD releasing abilities were investigated. Starch was able to be mixed better with PVA than with SA. Carbon-releasing process of PVA material containing starch follows second-order kinetic equation, and the release curve displayed a better double-reciprocal relationship. The saturated COD concentration released from per gram PVA material was 99.60 mg/(g·L). The effect of the two materials as sole carbon source