铜、锌离子对厌氧氨氧化污泥脱氮效能的影响.pdfVIP

中国环境科学 2014,34(4) ：924~929 China Environmental Science 铜、锌离子对厌氧氨氧化污泥脱氮效能的影响 * 李 祥,黄 勇 ,刘福鑫,袁 怡,陈钟姮,丁 敏 (1.苏州科技学院环境科学与工程学院,江苏 苏州 215011 ； 2.苏州科技学院环境生物技术研究所,江苏 苏州 215011) 摘要：通过接种厌氧氨氧化污泥,研究了 Cu2+ 、Zn2+浓度变化对厌氧氨氧化污泥脱氮效能长短期的影响.短期实验结果表明,铜、锌离子对 厌氧氨氧化污泥的脱氮效能影响主要分为 3 个阶段.刺激阶段,Cu2+浓度 0~1mg/L 和 Zn2+浓度 0~4mg/L 时,随着进水金属离子浓度的增加, 微生物活性受到刺激,氮去除速率迅速增加;稳定阶段,Cu2+浓度 1~8mg/L 时,氮去除速率处于稳定状态.抑制阶段,Cu2+浓度大于 8mg/L 和 Zn2+大于 4mg/L 时,随着进水金属离子浓度的增加,氮去除速率逐步下降.Cu2+ 、Zn2+对厌氧氨氧化污泥脱氮效能长期影响表明,当进水 Cu2+ 浓度达到 4mg/L 和 Zn2+达到 8mg/L 时厌氧氨氧化污泥的活性将受到抑制.降低进水重金属浓度后,厌氧氨氧化污泥活性可以得到恢复.厌氧 氨氧化菌对 Cu2+ 的敏感性强于Zn2+ . 关键词：厌氧氨氧化；铜离子；锌离子；氮去除速率；影响 中图分类号：X703.5,TQ028.8 文献标识码：A 文章编号：1000-6923(2014)04-0924-06 * Effect of Cu ( Ⅱ) and Zn ( Ⅱ) on nitrogen removal efficiency in anammox sludge. LI Xiang, HUANG Yong , LIU Fu-xin, YUAN Yi, CHEN Zhong-heng, DING Min (1.School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 2150l1, China ；2.Institute of Environmental Biotechnology, Suzhou University of Science and Technology, Suzhou 2150l1, China). China Environmental Science, 2014,34(4)：924~929 Abstract ：The effects of copper and zinc ion concentration on nitrogen removal efficiency were studied in short or long term by inoculating anammox sludge. The influence of copper and zinc ion in anammox sludge was mainly divided into three stages in the short-term. The stimulus phase, anammox bacteria activity was stimulated and the nitrogen removal rate increased rapidly with the increase of concentration of copper ion and zinc ion from 0mg/L to 1mg/L and from 0mg/L to 4mg/L respectively. The stabilization phase, the nitrogen removal rate in steady state with the concentration of copper ion increased from 1mg