土壤不同有机质组分对菲的吸附特征研究.pdfVIP

中国环境科学 2013,33(5) ：861~867 China Environmental Science 土壤不同有机质组分对菲的吸附特征研究 * 包桂奇,倪进治 ,魏 然,杨柳明 (福建师范大学地理科学学院,湿润亚热带生态地理过程教育部重点实验室,福 建 福州 350007) 摘要：采用批次实验,研究了三种不同类型土壤黄红壤、水稻土和草甸土的全土、重组、去松结态和紧结态 4 个组分对菲的吸附,结果表 明,菲在不同土壤及其组分上的吸附等温线都能用 Freundlich 方程进行拟合,所有等温线都具有一定程度的非线性,指数 N 值的大小顺序基 本都为全土重组去松结态紧结态.除了黄红壤的紧结态比去松结态对菲的吸附容量KF 值略小外,不同土壤及其组分对菲吸附的 KF 值以 及有机碳归一化的 KFoc 值大小顺序都为紧结态去松结态重组全土.不同类型土壤之间的 KF 值大小顺序为草甸土水稻土黄红壤,而 KFoc 值大小顺为水稻土草甸土黄红壤.KF 值与有机碳含量之间呈显著性正相关(P0.05),KFoc 与 N 之间呈极显著负相关(P0.001).土壤及 其组分对菲的吸附强度与有机质的结构特征和聚合程度有关. 关键词：土壤有机质；结合态腐殖质；菲；吸附 中图分类号：X53 文献标识码：A 文章编号：1000-6923(2013)05-0861-07 * Sorption characteristics of phenanthrene by different soil organic matter fractions. BAO Gui-qi, NI Jin-zhi , WEI Ran, YANG Liu-ming (Key Laboratory of Humid Subtropical Eco-geographical Process, Ministry of Education, School of Geographical Sciences, Fujian Normal University, Fuzhou 350007, China). China Environmental Science, 2013,33(5)： 861~867 Abstract ：Three fractions of organic matter (heavy fraction (HF), heavy fraction without the loosely combined humus (WLH), and tightly combined humus (TH) were separated from three soil types named yellow-red soil, paddy soil and meadow soil. Batch experiments were conducted to study the sorption of phenanthrene by HF, WLH, TH and bulk soils (BS). Results showed that all sorption isotherms of phenanthrene by the different organic matter fractions and bulk soils fitted Freundlich equation and were nonlinear in some degree. The values of Freundlich exponent coefficient (N) followed the order of BS HF WLH TH. The sorption capacity (KF) and its organic carbon normalized parameter (KFoc) for phenanthrene were in the order of TH WLH HF BS, except that KF of TH was less than t