La-Ni-O系薄膜复合材料氧敏性能研究.pdf

The of gas—sensingproperties researched．The concIusion hadbeen method major preparedbyso卜geI Cr3+ the Fe3+and fiIms，the incIuded：(i)ForLaB03(B=Cr、Fe、Co、Ni)thin were nOtJOhn-Tb¨er latticedistOrtlOnandthece¨VOlumes were iOns．thejr JOhn一。re¨er latticedistOrtiOnandthe C03+andNi3+were sma¨：But iOns，their ce¨voIumeswere and thinfIlmsthejr LaC003 Iarge．(ii)ForLaCr03，LaFe03 sheerresistancewas atrOOm andresistance— Very temperature high coefficient The thin稍lmhadIow untiI were temperature pOOr LaNi03 resjstiVjty 8000Cinamannersim¨artOthatofmeta¨ic∞nductOrs．andit wouId abOVe8000C．The charge—lransfer decompose oxygen．tO-metaI energy acrossthe metalseriesof dec哈ased t限nsition of cha阳cteristicsd—eIectronOfBions determinedthethinnIm mainly more Bion betterthe acti、，ity was，the properties．The oxygen—sensing characterOf lhin行Imwas． LaB03 The thin行lmbeen had LaNi03_6(06O．5)composi