无污染新工艺处理低品位软锰矿的研究.docVIP

湘潭大学 硕士学位论文 无污染新工艺处理低品位软锰矿的研究 姓名：魏学锋 申请学位级别：硕士 专业：环境工程 指导教师：田学达 ABSTRACT ABSTRACT Pyrolusite is an important raw material of preparing manganese sulfate, and about 60% manganese sulfate was produced by pyrolusite The key step of preparing manganese salt, with the pyrolusite as raw materials, is to turn Mn (Ⅳ) into Mn (Ⅱ), hence the type and characteristic of reducing agent in lixiviating are most important factors. Foundation:(ⅰ)The reducing agent is wide and cheap in conformity with the source, the best is the renewable resource products, namely organic matter; (ⅱ)This reducing agent is easy to process, and the processing course and using course are pollution-free; (ⅲ)Benefit to use and high resources recovery in the course of craft and high-quality of the products can be guaranteed. Two kinds of reducing agent have been confirmed through a series of screen testing with the low grade pyrolusite as raw materials, expressing with HYJ-01 and HYJ-02 separately. The trial indicates the two can react directly with pyrolusite in the sulphuric acid solution, and can reach ideal result of reducing. The craft parameters of using the two reducing agent were determined in the laboratory. While the liquid reducing agent HYJ-01 is applied, the optimum process conditions is that the entering reducing agent amount is 8.0 percent, the density of sulphuric acid is 30%, consumption of sulphuric acid is 120 percent times than value in theory, and response time is 30min; While using reducing agent HYJ-02 of solid state, the appropriate consumption of reducing agent HYJ-02 is 10 percent of the pyrolusite sample consumption; The reducing agent HYJ-02 grain size is about -120 eyes; A relatively suitable one of sulphuric acid is 30 percent of density, 120 percent times than value in theory is also appropriate consumption. Both - II - 提要  提  要  锰以化合物形式存在广泛分布于自然界中，在地壳中锰的平 均含量为 0.1%,占已知元素的第 15 位，由于它在冶金、化工、医 药、国防、机械、农业等行业的用途广泛，而越来越受到人们的 重视。硫酸锰是重要的锰盐，80%以上的锰盐都是由它加工制得。 软锰矿是生产硫酸锰的重