Chapter9紫外光谱.pptVIP

Ultraviolet Spectroscopy  紫外光谱 9.1 Basics of Ultraviolet Spectroscopy The UV involves the absorption of ultraviolet light by a molecule causing the promotion of an electron from a ground electronic state to an excited electronic state. The transitions are generally between a bonding or lone-pair orbital and an unfilled non-bonding or anti-bonding orbital. The wavelength of the absorption is then a measure of the separation of the energy levels of the orbitals concerned. 芳香族化合物的吸收（环状共轭体系） E1带(185nm, 50000)； E2带(200nm, 6900)； B带(230nm~270nm, 170)；结构精细； B带：芳环特征吸收带； 含取代基时，B带简化， 红移。 Inorgani