MgOAl2O3SiO2系尾矿微晶玻璃研究.pdfVIP

Studyonmineraltailings glass一ceramicsofMgO-A1203一Si02system Abstract Glass-Ceramics,whicharemadebycontrolledcrystallizationof glassesduringreheating,arepolycrystallinesolidmaterialshavingvery fine-grainedstructures.Thiskindofmaterialshavefairlywell-distributed glassphaseandcrystallinephase,featuringlowerexpansioncoefficient, highermechanicalstrength,strongercorrosion/weatheringresistantcapacity, andbetterheatresistance. Theadditionofnucleatingagentcangreatlyenhancesthecrystal nucleationinasuper-cooledglass,andisoneofthemostimportantmethods forthecontrolledcrystallizationofglass-ceramics.Somecompound nucleatingagent,suchasTi02,ZrO2,P20s，areusuallyused,buttheymust becapableofsolvingintoglassmeltsandthenenhancecrystalnucleation throughphaseseparationorbysegregatingsomefinecrystalsasthe substratesofheterogeneousnucleation.Baseglasswithoutnucleatingagent experiencesnodevitrificationintheheattreatmentprocess In the courses ofglass-ceramicformation,thebehaviors ofphase transformationarevery complicated Accordingto course ofphase transformationofm ost glass-ceramicsystems,itcouldbeapproximately dividedintotwomainstepsinsequence.Thatisliquid-liquidphase separation,crystalnucleationandgrowth. Heattreatmentisoneofthemostimportanttechnologicalprocedurein theformationofglass-ceramics.Usually,thereexistsanoptimunduration timeforheattreatmenttoeverykindofglass-ceramics,shorter,therebeing nosatisfyingoutcome;longer,theloweringofcrystallizationrateand coarsingofcrystalsbeingexisting.Thelatterisconfirmedinthispaper.The optimumnucleatigtemperatureiswithintherangeoft,and500Cupward. Environmentisthemostexigentproblemwefaced.Therearemore than200milliontonsofmetallictailingsproducedeveryyearinChinaand mostofthemwerediscardedastrash,resultinginpollutesofenvironment, deteriorationofecolasyandwastesofresources.InWulongtailings,the contentofSiO,ismorethan80%,whil