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21 5 Vol.21 No.5
2 0 0 7 10 CHINESE JOURNAL OF MATERIALS RESEARCH October 2 0 0 7
Ir VO2+/VO+ ∗
2
1,2 1 1
1. 100083
2. 100084
Ir , 50 Ir . , Ir
V()/V() , Ir V—O ,
. Ir , 20 mAcm−2
87.5%. , 6.9%, 25%.
, , Ir ,
TB333 1005-3093(2007)05-0542-05
Electrocatalytic activity of Ir–modified carbon felt for
VO2+/VO+ redox reaction
2
WANG Wenhong1,2 XUE Fangqin1 WANG Xindong1∗∗
1.The Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083
2.Beijing Pdcentury Technology Company, Beijing 100084
* Supported by National Natural Science Foundation of China No
Manuscript received January 10, 2007; in revised form May 25, 2007.
** To whom correspondence should be addressed, Tel:(010 E–mail: Echem@ustb.edu.cn
ABSTRACT The carbon felt was modified by pyrolysis of Ir from H IrCl . After 50 charge-discharge
2 6
cycles, much of the Ir metal still cohere with the fibres, indicating the stability of Ir in vanadium flow cell
electrolyte. The Ir-modified carbon felts had improved activity and lowered overpotentials for the desired
V()/V() redox processes. The kinetics mechanism was studied for the VO2+ /VO+ couple, and a
2
chemical reaction step suggested follow the irreversible electron transfer step. The Ir-modified electrode
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