三聚氰胺改性沥青基球形活性炭实验研究.pdfVIP

第4卷 第12期 2009 年 12 月 中国科技论文在线 Sciencepaper Online 893 三聚氰胺改性沥青基球形活性炭的实验研究 刘小军，詹 亮，梁晓怿，乔文明，凌立成 （华东理工大学化学工程联合国家重点实验室，上海 200237 ） 摘 要：以三聚氰胺为改性剂，修饰了沥青基球形活性炭的表面化学性质。分别采用热重分析仪(TGA)、气体吸附仪、 X射线光电子能谱仪(XPS)等对球形活性炭改性前后的性质进行了分析与表征。结果表明：浸渍三聚氰胺高温处理改性 是一种有效的修饰沥青基球形活性炭表面化学性质的方法。通过调节球形活性炭与改性剂的浸渍比，能够获得具有不 同孔隙率和氮元素含量的沥青基球形活性炭。在球形活性炭与改性剂的浸渍比为 1 ∶0.8 时，改性球形活性炭的BET 比 2 2 表面积从改性前的 1 000 m /g下降到 795 m /g ，其氮元素含量相应从0.3%增加到 5.4% ，氮在球形活性炭表面的存在形 式为吡啶和吡咯类氮。 关键词：材料科学；活性炭；改性；三聚氰胺 中图分类号：TQ425.1 1 文献标识码：A 文章编号：1673－7180(2009)12 －0893 －7 Experimental study of pitch-based spherical activated carbon modified with melamine Liu Xiaojun ，Zhan Liang ，Liang Xiaoyi ，Qiao Wenming ，Ling Licheng (State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China) Abstract: Pitch-based spherical activated carbon (PSAC) was modified with melamine. The properties of PSAC before and after modifications were investigated by theoremgravity analysis(TGA), N2 adsorption, and XPS, et al. The results show that N-containing functional groups can be effectively introduced into PSAC by modification with melamine. The mass ratio of PSAC to melamine has great effect on the porosity and N content of the modified PSAC. When the PSAC impregnated with melamine according to the ratio of 1 ∶0.8, the BET specific surface area of the sample decreases from 1 000 m2/g to 795 2 m /g, and the mass fraction N increases from 0.3% to 5.4%. The nitrogen atom exists in the form of pyridine and pyrrole. Key words: material science ；activated carbon ；modification ；melamine 主要是指活性炭的比表面积、孔容及孔径分布，决定了 0 引 言