纳米金属与有机分子共掺杂超分子结构光电子材料功能设计_李贵安.pdfVIP

第36 卷 第2 期 陕西师范大学学报( 自然科学版) Vol.36 o.2 2008 年3 月 Journal of Shaanxi ormal University ( atural Science Edition) Mar. 2008 :2008) 李贵安, 张玉荣, 马少华 ( , 710062) :提出了一种基于纳米金属与有机分子共掺杂超分子结构光电子材料的设计组装 方法.通 过分子在球形金属纳米粒子表面吸附形成的超分子结构实现金属纳米粒子对分子的激发, 进而达 到分子功能增强与扩展. 讨论了材料设计过程中的几个关键问题, 设计并合成出具有短波长光存储 特性复合材料薄膜. 实验表明, 与单纯由甲基橙掺杂复合膜相比, 甲基橙在具有超分子结构的复合 膜中, 最大吸收波长蓝移约23 nm, 复合膜迅速分解的初始温度和分解温度带的范围分别提高和降 低41 和51 .表明以这种思路设计组装光电子功能复合材料的方法有效可行. : 纳米复合功能材料; 超分子结构; 功能设计 : TB333; O437 : A Functional design of optoelectronic materials codoped by metal nanoparticles and organic molecules based on supramolecule structure LI Guian, ZHA G Yurong, MA Shaohua (College of Physics and Information Technology, Shaanxi ormal University, Xian 710062, Shaanxi, China) Abstract: A new method for design and assembling of functional materials was presented based on the supramolecule structure by the codoping of nanosized metal and organic molecules. With the supra molecule structure, in which the molecules were adsorbed onto the surface of spherical metal nanoparticles, the excitation of metal nanoparticles on molecules was realized, and the functional extension and enhancement of molecules were achieved. The key issues related to the design were discussed and analyzed. The composite material films with the properties of optical storage in short wavelength were designed and synthesized experimentally. The results show that, compared with the composite film doped by Methyl orange ( MO) , the maximum absorption wavelength of MO in composite film with supramolecular structure was blueshift about 23nm. T he initial decomposition