氨基改性淀粉GMA共聚物对Pb(II)吸附性能.pdfVIP

氨基改性淀粉GMA 共聚物对Pb(II)的吸附性能∗ 谢国仁，尚小琴*，刘汝峰，胡晶，刘玉珍 （广州大学化学化工学院，珠江三角洲水源保护与水质安全教育部重点实验室（广州大学），广州 510006 ） 摘要：以木薯淀粉为原料，通过接枝共聚、环氧开环反应，得到富含-NH2 官能团的新型氨基改性淀粉(AMS)， 用FT-IR 和SEM 对其结构进行表征。在静态条件下，研究了AMS 对水溶液中Pb(II) 的吸附性能和吸附热 力学，考察了溶液pH 值、吸附时间、Pb(II)初始浓度及温度对AMS 吸附性能的影响。结果表明：pH 值对 AMS 的吸附性能有显著影响；该吸附是一个快速吸附过程，符合准二级动力学方程，以化学吸附为主；吸 附等温线用Langmuir 方程拟合效果优于Freundlich 方程。 关键词：木薯淀粉；淀粉接枝甲基丙烯酸缩水甘油酯；氨基改性淀粉；吸附；Pb(II) 中图分类号：TQ 316.343 文献标识码：A 文章编号0000-0000（2010 ）00-0000-00 Adsorption properties to Pb( Ⅱ) on grafted copolymer of glycidyl methacrylete onto starch modified with amino-group XIE Guoren, SHANG Xiaoqin*, LIU Rufeng, HU Jing, LIU Yuzheng （School of Chemistry and Chemical Engineering of Guangzhou University; Key Laboratory of Safety and Protection of Water Quality in the Pearl River Delta, Ministry of Education (Guangzhou University), Guangzhou 510006 China ） Abstract: A novel amino modified starch (AMS) adsorbent modified with ethylenediamine had been obtained via grafting polymerization and ring-opening reactions using cassava starch as raw material. The adsorbent was characterized by FT-IR and SEM. The absorption properties and adsorption thermodynamics were studied in the adsorption process of Pb( Ⅱ) ions in aqueous solution on AMS. The effects of pH valves, adsorption time, temperature and initial concentration were considered. It was found that the effect of pH on adsorption is visible. The adsorption which ∗ 基金项目：广东省自然科学基金项目（9151009101000036 ）；广东省科技攻关项目（0711051900013 ）；广州市科技支撑项目 （2009Z1-E531 ）联系人:尚小琴，教授，从事淀粉等天然高分子材料的改性，电话： hushanren@163.com 第一作者:谢国仁（1987-），男，硕士研究生，378543540@ 。 1 is fast followed a pseudo-second order process, chemical adsorption is the main adsorption