超分子中主体热分解行为的多样性分析――残存态环糊精的热分解.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) April Acta Phys. Chim. Sin., 2008, 24(4) ：729-736 729 [Review] 超分子中主体热分解行为的多样性分析———残存态环糊精的热分解 鹏 宋乐新* ( 国科学技术大学化学系, 合肥 230026) 摘要: 指出了只有在主 客体超分子化学 才能出现的主体热分解行为多样性现象, 提出了所谓的残存态主体 (survived host)的概念. 残存态主体意指主客体超分子失去客体后的产物, 它是由分子间弱相互作用所引起的主 客体包合现象的有力佐证. 以残存态环糊精(survived CD)为着眼点, 仔细比较了游离态CD、CD 包合物即包结态 CD 与残存态CD 的热分解行为差异性, 据此指出了有关文献在进行包结态CD 热分解动力学计算时, 将残存态 CD 当成包结态CD 处理的一个概念错误. 关键词: 环糊精; 超分子; 包合物; 动力学; 热分解 中图分类号: O643 Analysis of Thermal Decomposition Behavior Diversity of Host in a —Thermal Decomposition of Survived Cyclodextrin Supermolecule—— XU Peng SONG Le Xin* (Depa rtment of Chemistry, University of Science and Technology of China, Hef ei 230026, P. R. China) Abstract: The diversity of thermal decomposition behavior of host in a host guest supermolecule was described in detail. The concept of a survived host was given. A survived host means the product of a host guest supermolecule losing its guest after heated. It served as a powerful evidence for the weak intermolecular interaction between host and guest in inclusion phenomenon. Focused on survived cyclodextrin (survived CD), the present work carefully compared the differences of thermal decomposition behavior among free CD, complexed CD, and survived CD, and pointed out an important conceptual error which had occurred in some papers due to a lack of appreciation of the relationship between survived CD and complexed CD. Key Words: Cyclodextrin; Supermole