不锈钢表面硅烷复合膜的制备及抗海水腐蚀研究.pdfVIP

The 6th China Corrosion Conference Preparation of Silane Complex Films on Stainless Steel Surface and Corrosion Resistance Study in Seawater Shougang CHEN, Shunan XING, Xianwang SONG, Yunping LIU Institute of Materials Science and Engineering, Ocean University of China, Qingdao, China Email: sgchen@ouc.edu.cn Abstract: The bis- [triethoxysilylpropyl] tetrasulfide (BTESPT) silane film and containing Ti silane hybrid film have been prepared on 304 stainless steel surface successfully using the dip-coating method. Scanning electronic microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS) were applied to characterize the micro-morphology and element constitution of different films. The anti-corrosion properties of the BTESPT silane film and containing Ti silane hybrid film were studied by the potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in aerated 3.5 wt.% NaCl solution. Experimental results show that BTESPT silane film has commendable protection against corrosion for substrates, postponing the corrosion progress, and the protection of BTESPT/TiO2 hybrid film is better than BTESPT film for 304 stainless steels. Keywords: silane; hybrid film; titanium (IV) oxide; corrosion 不锈钢表面硅烷复合膜的制备及抗海水腐蚀研究 陈守刚，邢树楠，宋现旺，刘云平 中国海洋大学材料科学与工程研究院，青岛，中国，266100 Email: sgchen@ouc.edu.cn 摘 要：本论文采用浸渍法在 304 不锈钢表面分别制备了双-[3-(三乙氧基)硅丙基]四硫化物硅烷膜和 含钛硅烷杂化膜（钛酸四丁酯为钛源）。利用扫描电子显微镜（SEM ）和X 射线能谱分析（EDS ）能 谱表征了膜层的表面形貌和元素组成，借助电化学阻抗谱(EIS)、动电位极化曲线等技术研究了硅烷膜 及含钛硅烷复合膜在3.5wt.%NaCl 溶液中的抗腐蚀性能，实验结果表明硅烷膜对不锈钢基体有很好的 保护作用，延缓了它的腐蚀进程，且含钛硅烷膜对不锈钢的保护作用要优于硅烷膜。 关键词：硅烷；杂化膜；二氧化钛；腐蚀 1 引言