固相分散萃取与气相色谱_负化学离子源质谱联用法测定食品中三唑醇的残留量.pdfVIP

2008 7 V o l. 26 N o. 4 Ju ly 2008 Ch inese J ourna l of Chrom atog rap hy 515~ 518 沈伟健, 林 宏, 赵增运, 丁 涛, 徐锦忠, 沈崇钰 (, 2 10001) : ( 1% ), , , , 0001 m g/ kg 0003 m g / kg 0050 ~ 0750 m g / L, 0994 7 0005, 00 10, 0020 m g / kg 3 70% ~ 110% , 120% : : O658 : A : 100087 13( 2008 : Determ ination of triadimenol residue in foodsw ith dispersive solid phase extraction cleanup by gas chromatography negative chem ical ionization mass spectrometry SHEN W e ijian, L I N Hong, ZHAO Zengyun, D ING Tao, XU Jinzhong, SHEN Chongyu (F ood La bora tory of J ian gsu En try Ex it n spection and Qu ar an tin e Bu r eau , Nan j in g 210001, China ) Abstract: A confirm atory m ethod is presen ted for the determ ination o f tr iadim eno l residue in foods by dispersive solid phase extractiongas chrom atographynegative chem ical ion ization m ass spectrom etry ( SPEGCNCI/M S). Tr iad mi enol res idue w as ex tra cted from d ifferen t food sam p les, such as snow pea, carrot, orange, bean, sp inach, oolong tea, r ice, beef, longsnout catfish, roye l jelly, red sw am p cray fish, bee honey etc w ith aceton itr ile contain ing 1% acetic acid and smi u ltaneous liqu idliqu id partition ing form ed by adding anhydrous m agnesium su lfate p lus sod ium acetate, fo llow ed by a smi p le cleanup step know n by d ispersive so lidphase extraction. The aliquot w as determ ined and con firm ed by gas chrom atographynegative chem i cal ion ization m ass spectrom etry using external standard m ethod. The av