A_general_strategy_for_nanocrystal_synthesis教程.pdf

Vol 437|1 September 2005 |doi:10.1038/nature03968 LETTERS A general strategy for nanocrystal synthesis Xun Wang1,2, Jing Zhuang1,2, Qing Peng1,2 Yadong Li1,2 New strategies for materials fabrication are of fundamental of ,0.22 nm, which corresponds to the (111) planes of face-centred 1–12 importance in the advancement of science and technology . cubic Ir. EDS (energy dispersive spectroscopy) microanalysis and Organometallic13,14 and other organic solution phase15–17 synthetic powder XRD (X-ray diffraction) (Fig. 2a) measurement have proven routes have enabled the synthesis of functional inorganic quan- the successful synthesis of face-centred cubic structured Ag (JCPDS tum dots or nanocrystals. These nanomaterials form the building 4-783), Au (JCPDS 4-784), Pd (JCPDS 46-1043), Pt (JCPDS 4-802), blocks for new bottom-up approaches to materials assembly for a Rh (JCPDS 5-685), Ir (JCPDS 46-1044) and hexagonal Ru (JCPDS range of uses; such materials also receive attention because of their 6-663). 18–21 intrinsic size-dependent properties and resulting applications . The primary reaction in the preparation of noble metal nanocrys- Here we report a unified approach to the synthesis of a large tals through this liquid–solid–solution (LSS) process involved the variety of nanocrystals with different chemistries and properties reduction of noble metal ions by ethanol at the interfaces of metal and with low dispersity; these include noble metal,