磁性多壁碳纳米管吸附去除水中罗丹明B与研究.docVIP

中国环境科学 2008,28(11)：1009~1013  China  Environmental Science  磁性多壁碳纳米管吸附去除水中罗丹明 B 的研究  王  彬,龚继来,杨春平*,曾光明,周雯婧 (湖南大学环境科学与工程学院,湖南 长沙 410082)  摘要：多壁碳纳米管(MWNTs)用硝酸处理后,利用化学共沉淀的方法制备了磁性多壁碳纳米管.利用扫描电子显微镜(SEM),X 射线衍射分 析仪(XRD)和 zeta 电位测定仪对其进行了表征,并研究了它对水中罗丹明 B 的吸附性能.考察了吸附动力学、吸附等温线及吸附剂用量对 吸附性能的影响.结果表明,磁性多壁碳纳米管在吸附时间为 7.5h 时对罗丹明 B 的去除率可达 87.5%,最大吸附量可达 11.02mg/g.该吸附剂 具有良好的磁性能和吸附性能,能有效去除罗丹明 B,经磁分离,吸附剂很容易从废水中分离出来.等温吸附数据符合 Langmuir 模型,吸附反 应过程符合 Langergren 准一级动力学方程. 关键词：多壁碳纳米管；磁性材料；罗丹明 B；吸附性能 中图分类号：X 703 文献标识码：A 文章编号：1000-6923(2008)11-1009-05  Removal of rhodamine B from aqueous solution by magnetic multi-wall carbon nanotubes. WANG Bin, GONG Ji-lai, YANG Chun-ping*, ZENG Guang-ming, ZHOU Wen-jing (College of Environmental Science and Engineering, Hunan University, Changsha 410082, China). China Environmental Science, 2008,28(11)：1009~1013 Abstract：Multi-wall carbon nanotubes / iron oxide magnetic composite was prepared using chemical co-precipitation after multi-wall carbon nanotubes (MWNTs) were purified by nitric acid solution. The magnetic composite obtained was characterized by SEM, powder XRD and zeta SIZER. In addition, the adsorption kinetics, adsorption isotherm and effects of adsorbent dosage on magnetic composite adsorption ability were discussed in detail. The removal rate of rhodamine B reached to 87.5% at 7.5h and the maximum adsorption was 11.02mg/g. The adsorbent had good adsorption properties and could be well separated from aqueous solution by a permanent magnet. The sorption isotherm coincided with Langmuir model, the sorption processes coincided with Langergren pseudo-first-order kinetics equation. Key words：multi-wall carbon nanotubes；magnetic material；rhodamine B；adsorption capacity  染料废水一般具有复杂的芳环结构,难于直 接生物降解,往往要结合其他处理方法如吸附、  性颗粒后对离子型染料罗丹明 B 的吸附性能, 为开发新的水处理材料提供参考. - 成本低,效率高,简单易操作并对有毒物质不敏感 等优点 ,而被认为优于其他的染料废水处理技  1 1.1  实验部分 材料 术 [4].碳纳米管作为一种新型的吸附材料,具有比 表面积大、吸附容量大的优点,引起了人们广泛 的关注.近年来,研究者们或直接将碳纳米管作吸 - 物和无机物的吸附.吸附剂的固体颗粒物,除结构 硫酸亚铁铵(NH4)2Fe(SO4)2·6H2O)(分析纯