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Sensors 2011, 11, 1924-1931; doi:10.3390/s110201924
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Article
Effect of TiO on the Gas Sensing Features of TiO /PANi
2 2
Nanocomposites
Duong Ngoc Huyen *, Nguyen Trong Tung, Nguyen Duc Thien and Le Hai Thanh
Institute of Engineering Physics, Hanoi University of Science and Technology, No.1, Daicoviet,
Hanoi, Vietnam; E-Mails: trongtung227@ (N.T.T.); ducthien_ly@ (N.D.T.);
haithanh@.vn (L.H.T.)
* Author to whom correspondence should be addressed; E-Mail: duonghuyen@.vn;
Tel.: +84-438-693-350; Fax: +84-438-693-498.
Received: 11 January 2011; in revised form: 25 January 2011 / Accepted: 28 January 2011 /
Published: 1 February 2011
Abstract: A nanocomposite of titanium dioxide (TiO ) and polyaniline (PANi) was
2
synthesized by in-situ chemical polymerization using aniline (ANi) monomer and TiCl4 as
precursors. SEM pictures show that the nanocomposite was created in the form of long
PANi chains decorated with TiO2 nanoparticles. FTIR, Raman and UV-Vis spectra reveal
that the PANi component undergoes an electronic structure modification as a result of the
TiO2 and PANi interaction. The electrical resistor of the nanocomposite is highly sensitive
to oxygen and NH3 gas, accounting for the physical adsorption of these gases. A
nanocomposite with
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