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外文原文:
Photocatalytic degradation of organic wastes by electrochemically assisted TiO2 photocatalytic system
Junshui Chen, Meichuan Liu, Jidong Zhang, Xiangyang Ying and Litong Jin, Department of Chemistry, East China Normal University, Shanghai, 200062, China Received 11 October 2002;? revised 30 August 2003;? accepted 23 September 2003.?; Available online 17 December 2003.
Abstract
Photocatalytic degradation of organic wastes with nanosized titanium dioxide particles has been studied for a long time in order to offer an appropriate method for wastewater treatment, but its practical application is greatly limited by the slow process. In this work, an electrochemically assisted TiO2 photocatalytic system was set-up by combining a TiO2 photocatalytic cell with a three-electrode potentiostatic unit. The composite system revealed high photocatalytic activity towards organic wastes mineralization. After continuous treatment for 0.5 h, the maximum absorption of rhodamine 6G (R-6G) was reduced by more than 90%; chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) of textile dye wastewater (TDW) were decreased by 93.9 and 88.7%, respectively. The biodegradability of TDW was also improved because the COD/BOD5 ratio decreased from 2.1 to 1.2. All these results indicated that the composite system could be used for effective organic wastes mineralization or as a feasible detoxification and color removal pretreatment stage for biological post treatment.
Author Keywords: Titanium dioxide; Rhodamine 6G; Hydroxyl radical; Electrolysis; Wastewater
Article Outline
1. Introduction
2. Experimental
2.1. Chemical reagents
2.2. Apparatus
2.3. Photoreactivity
2.4. Characterization techniques
3. Results and discussion
3.1. Hydroxyl radical generation in electrochemically assisted TiO2 photocatalytic system
3.2. Comparison of rhodamine 6G degradation in different combination patterns
3.3. Photocatalytic characteristics of rhodamine 6G degradation
3.4. Wastewater t
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