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The Analysis of Characterizations and Sources of ambient VOCs in Guangzhou
Abstract Because Volatile organic compounds (VOCs) are important precursors for ozone photochemical
formation, researching the characterizations and sources of VOCs is very rewarding. VOCs were measured from
March 2011 to March 2012 in Pan Yu Atmospheric Composition Station, Guangzhou with the purpose of
analyzing characterizations and sources of VOCs. At the same time, in order to better analyze the sources of VOCs,
the industrial sites around the sampling site, different VOCs chemical life and meteorological condition need to be
comprehensive considered. The results show that the monthly concentration variation of VOCs ranges from
40.99ppbv to 65.40ppbv and its monthly average concentration is 47.95ppbv. Meteorological factors have an effect
on concentrations of VOCs, especially when the wind directions are ENE and SW and the wind speeds are
relatively slow, which contribute to the accumulation of VOCs in sampling site. The temperature has an
anti-relation with the concentration of VOCs. VOCs composition characterizations in sampling site is similar to the
industrial city Dongguan. In the analysis of sources of VOCs in sampling site, isoprene is emitted from the local
vegetation by three methods (Scatter plots for isoprene versus 3-methylpentane, cis-2-Butene, temperature and
diurnal variation of isoprene) and BTEX (benzene, toluene, ethyl benzene, m/p-xylene) are emitted from industries
in the eastern city Dongguan which can be judged from chemical lifetime, transport time and wind direction.
Different air parcels have an effect on composition characterizations of VOCs with the large proportion of
aromatics when the air parcel went through Dongguan and with the large ratio of alkenes when the air parcel c
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