微波强化臭氧氧化降解苯酚水溶液.pdfVIP

g 第 6O卷 第 12期 化 工 学 报 Vo1．6O No．12 2009年 12月 CIESC Journal December 2009 ，11声 微波强化臭氧氧化 降解苯酚水溶液 赵德明 2 李 敏 ，张建庭 ，金宁人。，徐新华 ，汪大晕 (浙江大学环境与资源学院，浙江 杭州 310027；。浙江工业大学化学工程与材料学院，浙江 杭州 310032) 关键词 ：微波；臭氧 ；苯酚 ；协 同效应 ；动力学 中图分类号：X 78；TQ209 文献标识码 ：A 文章编号 ：0438--1157(2009) 12--3137一O5 Degradationofphenolaqueoussolution by microwaveenhancedozoneoxidation ZHAO Deming-一，LIM in2，ZHANG Jianting2，JIN Ningren2，XU Xinhua ，W ANG Dahui (CollegeofEnvironmentalandResourceSciences，ZhejiangUniversity，Hangzhou310027 Zhejiang，China；。CollegeofChemicalEngineeringandMaterials，ZhejiangUniversity ofTechnology，Hangzhou310032，Zhejiang，China) Abstract：Thedegradation ofphenolin aqueoussolutionwith thecombination ofmicrowaveandozone (MW ／O3)wasstudiedwithlaboratory—scaleexperiments．Effectsofozonedose，pHvalue，initialphenol concentration and reaction temperature on the reaction kinetics were investigated．In all cases， the degradationofphenolfollowsapseudo—first—orderkinetics relation．MW ／O3combined technology is favorableforenhancing theremovalefficiencyofphenol，with theenhancementfactorofthefirst—order kineticsconstantbeingaround3．6．ExperimentalresultsshowedthatthesynergeticeffectofMW ／O3 combinedtechnologywasobviousandupto99％ ofphenolwasremovedafter30minreactionwithinitial phenolconcentrationof100mg ·L ，ozonedoseof1．1mg ·min ，pH valueof9— 11，andreaction temperatureof25oC． Keywords：microwave；ozone；phenol；synergeticeffect；kinetics 酚