不锈钢基膜论文：不锈钢中空纤维基膜制备与表征.docVIP

不锈钢基膜论文：不锈钢中空纤维基膜制备与表征 【中文摘要】本文运用非溶剂致相转化法(NIPS)制备了不锈钢中空纤维基膜前驱体,对其进行烧结得到不锈钢中空纤维基膜,采用密度、孔隙率、最大孔径、机械强度、通量、扫描电镜(SEM)等表征手段对烧结后的基膜进行表征,探讨了制备工艺对烧结后基膜性能的影响,具体结果如下：首先,制备了聚丙烯腈(PAN)、聚砜(PSF)、聚醚砜(PES)不同种聚合物的不锈钢微粉铸膜液,研究了不同悬浮液分散体系的流变性能以及稳定性能,不同铸膜液体系粘度都呈剪切变稀的特性,而且随聚合物浓度的增加而增大,最终确定选用PAN作为铸膜液的聚合物。其次,当铸膜液体系粘度为10000 mPas左右时,采用NIPS法纺制PAN体系的中空纤维基膜前驱体形态较好,基膜前驱体的密度以及机械强度随PAN含量的增大而增大,孔隙率随PAN含量的增大而减小,少量添加剂PVP可以提高前驱体的密度、孔隙率以及机械性能。第三,对基膜前驱体进行烧结制得的不锈钢中空纤维基膜随着PAN浓度的增大,烧结后基膜微观结构越来越致密,导致密度增大,孔隙率变小,最大孔径也减小,机械强度增大,通量减小。在1100-1350℃范围内,烧结温度越高,烧结后基膜密度变大孔隙率减小,最大孔径变小,机械强度升高,但通量下降。随着烧结气氛中H2含量的增大,烧结后基膜的密度减小,孔隙率增大,最大孔径增大,机械强度下降,通量升高。最后,加入0.5%的PVP可以适当提高烧结后基膜的致密程度,增加基膜密度,提高机械性能。添加5%的铝粉后,烧结后基膜的机械强度大大提高,比没有添加铝粉的提高了接近3倍左右,但通量大大减小。铝粉的加入可以适当减小烧结后基膜的孔径,但改变不大。不同条件烧结的基膜纯水通量随时间而衰减,最终趋于稳定。 【英文摘要】In this paper, stainless steel support membrane precursor was prepared by non solvent induced phase separation (NIPS) method and was sintered to become stainless steel support membrane which was characterized by various methods including density, porosity, maximum diameter, mechanical properties, flux, SEM and so on. The effect of preparing process on membrane performance after sintering was also explored.Firstly, stainless steel powder casting solution with different polymer including polyacrylonitrile (PAN), polysulphone (PSF), polyethersulfone (PES) were prepared. The rheological property and stability of different casting solution were also studied and the result showed that the casting solution viscosity went down as the shear rate went up and grew up as the content of polymer increased. At last, PAN was chosen as the proper polymer of casting solution.Secondly, the shape of PAN system hollow fiber support membrane precursor prepared by using NIPS method was better when viscosity of casting solution was about 10000 mPas. The density and mechanical properties of support precursor went up as the content of PAN went up while the porosity went down. A little bit additive PVP could improve the density, porosity and mechanical p