甲基丙烯酸_丙烯酰胺双单体共聚反蛋白石光子晶体的制备.pdfVIP

2012 年第70 卷 化 学 学 报 Vol. 70, 2012 第5 期, 611～616 ACTA CHIMICA SINICA No. 5, 611～616 ·研究论文· 甲基丙烯酸/丙烯酰胺双单体共聚反蛋白石光子晶体的制备 傅小勤 郭 明* 武 嘉 战胜鑫 (大连大学环境与化学工程学院 大连 116622) 摘要 以烧结后的二氧化硅光子晶体为模板, 采用溶胶凝胶法向模板间隙填充以甲基丙烯酸(MAA)和丙烯酰胺(AM) 为双功能单体, N,N-亚甲基双丙烯酰胺(BIS)为交联剂的聚合物前驱液, 制备了甲基丙烯酸/丙烯酰胺共聚(PMAM)双单 体反蛋白石凝胶光子晶体. 通过紫外可见光谱分析表明, 反蛋白石结构的凝胶膜对pH 响应范围在4.0～7.0 之间. 由于 其不受离子强度的影响, 除了可以作为pH 传感器外, 还可以作为金属离子及生物小分子等分子印迹光子晶体传感器的 基体膜. 关键词 二氧化硅光子晶体; 反蛋白石光子晶体; 垂直沉积; 烧结 Preparation of the Polymethacrylic and Polyacrylamide Inverse Opal Photonic Crystals Fu, Xiaoqin Guo, Ming* Wu, Jia Zhan, Shengxin (College of Environmental and Chemical Engineering, Dalian University, Dalian 116622) Abstract The polymethacrylic and polyacrylamide inverse opal photonic crystals films (PMAM) have been prepared by using the sintered silica photonic templates, during which the photonic templates are infil- trated by the precursor solutions with the methacrylic and the acrylamide bi-functional monomer, and then polymerized under the UV light (365 nm) and in the end the polymerized films are immersed in HF solu- tions for the remove of templates. By the analysis of UV/Vis spectra, with the pH increasing, their UV/Vis spectrum peaks are red-shifted at pH ＝4.0～7.0. But they have no response to the ionic strength, so they can provide the potential matrix membrane for preparing the pH sensors, metal ions and small biomolecules im- printed photonic crystal sensors. Keywords silica photonic crystals; inverse opal photonic crystals; vertical deposition; sinter