014_汽油催化改质反应过程数值模拟.pdfVIP

2006 年用户年会论文 汽油催化改质反应过程数值模拟 侯栓弟∗ 龙军 郭湘波 朱丙田 张占柱 石油化工科学研究院，北京 100083 [ 摘 要 ] 在汽油催化反应动力学模型和气固两相流动模型的基础上，建立了汽油改质反应过程流动—反应 耦合模型。针对不同的转化反应器构型—提升管、提升管-床层反应器，对汽油改质过程进行了 数值模拟。模拟结果表明，对提升管反应器而言，汽油经过低温改质反应后，烯烃含量可以从 35.1%降低到 15%左右，烯烃降低幅度可达 57%，汽油中烯烃主要转化为异构烷烃。另外，随 着反应温度的升高，汽油转化反应中的裂化反应增强，导致汽油收率下降。对于提升管-床层反 应器而言，汽油中的烯烃含量可以降得更低，在床层空速 4 时，烯烃含量可以降低到 5%左右， 汽油收率为 80m%左右。 [ 关键词 ] 数值模拟 流动反应模型 提升管 催化裂化 Numerical Simulation of FCC Gasoline Catalytic Conversion Process Hou shuandi Long jun Guo xiangbo Zhu bingtian Zhang zhanzhu Research institute of Petroleum Processing Beijing, 100083 [ Abstract ] Based on the gas-solid two-phase turbulent model and kinetic model of FCC gasoline catalytic conversion, a reaction-flow coupled model was built to simulate FCC gasoline conversion process in riser and riser-bed reactor. For riser reactor, the simulation result shows that mass fraction of olefin component is decreased from 35m% to 15m%, and most of olefin is converted to isoparaffin component, which is useful to maintain the gasoline octane rating. With the reaction temperature increasing, the cracking reaction is enhanced, and the LPG ∗ 通讯联络人。通讯地址：北京 914 信箱 58 分箱，100083，Email ：housd@ 2006 年用户年会论文 yield is dramatically increased when the reaction temperature beyond 450℃. For the riser-bed reactor, the mass fraction of olefin can be reduced to a very low lever, 5m% olefin in gasoline product when reaction temperature is 400℃, MHSV is 2, while the gasoline yield is only about 80m%. [ Keyword ] Fluid