活性白土化学改性及作用机理的研究.pdfVIP

35 3 : V o l 35 N o 3 2010 6 Jou rna l of G u angx iU niversity: N a t Sc i Ed June 2010 : 100 17445 ( 20 10) 高晓薇, 韦藤幼, 潘远凤, 童张法 ( , 530004) : , , Ca( OH ) 2 , Ca( OH ) 2, B ron sted L ew is, , 1404 mmo l/ g; , B ron sted, , 0775 mm o l/ gMM TXRD , , ; , , : ; ; : TD875 : A Study on chem icalmodification of activated clay and itsmechanism GAO X iaow e,i W E I T engyou, PAN Y uanfeng, TONG Zhangfa ( Co llege of Chem istry and Chem ical Eng inee ring, G u angx iU niversity, N ann ing 5 30004, Ch ina) Abstract: T he act ivated clay w ith the largest b leach ing rate w ere organically m odified by Ca( OH ) 2 and those w ith the largest activated degree w ere organically m od ified by cety ltrmi ethy l am ine to study the chem ical m od ification and m ech anism o f the act ivated clayT he results show ed th at reac t ion took p lace not only in the activated centers o f B ron sted ac id but a lso in those o f Lew is acid and th at the modified am ount w as 1404 mm o l/ g w hen the act ivated c lay w ere m od ified by Ca( OH ) 2 H ow ever, reaction took place on ly in the activated centers of Bronsted acid and the m od ified am oun t w as 0775 mm ol/g MMT when the activated c lay w ere m odified by cety ltrmi ethy l am ineM ean w hile, XRD ana lysis ind icated th at the layer distant o f a ll m od if ied activated c lays w as increased The reaction u sing m onova lent cation m odifiersw as easily carried out and the smi ple w et processw as enough fo r produ ction W hereas, the reaction u sing d iva lent cation one w as m ore diff icult and the h a lfdry process w ith low temp erature